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Nafion改性多级孔径石墨烯气凝胶制备与性能研究

王勇 于云 冯爱虎 江峰 胡学兵 宋力昕

无机材料学报2018,Vol.33Issue(4):469-474,6.
无机材料学报2018,Vol.33Issue(4):469-474,6.DOI:10.15541/jim20170165

Nafion改性多级孔径石墨烯气凝胶制备与性能研究

Nation Modified Graphene Aerogel with Hierarchical Porous Structures

王勇 1于云 2冯爱虎 1江峰 1胡学兵 2宋力昕1

作者信息

  • 1. 中国科学院上海硅酸盐研究所无机涂层重点实验室,上海200050
  • 2. 中国科学院大学,北京100049
  • 折叠

摘要

Abstract

A novel graphene aerogel with pore size less than 1 μtm was synthesized by Sol-Gel method,in which Nation was skillfully introduced as modifiers connecting graphene oxides (GO).Ethylenediamine was used to produce a chemically linked graphene hydrogel during reducing process,which can then be freeze-dried to remove the absorbed water to form graphene aerogel.Nafion in GO solution prohibits the re-stacking of individual graphene sheets during reduction and freeze-drying process.By the above method,the pore size of as-prepared graphene aerogel could be effectively controlled within 1 μm,much less than that of the traditional graphene aerogel (20-100 μm).The new graphene aerogel with unique structure exhibited excellent properties,such as high specific surface area,high porosity,and better electrochemical properties.All data suggest that this graphene aerogel may have promising application prospect in the field of energy.

关键词

三维石墨烯/石墨烯气凝胶/石墨烯/氧化石墨烯/Nation

Key words

three-dimensional graphene/graphene aerogel/graphene/graphene oxide/Nafion

分类

化学化工

引用本文复制引用

王勇,于云,冯爱虎,江峰,胡学兵,宋力昕..Nafion改性多级孔径石墨烯气凝胶制备与性能研究[J].无机材料学报,2018,33(4):469-474,6.

基金项目

National Natural Science Foundation of China (51662019) (51662019)

无机材料学报

OA北大核心CSCDCSTPCDSCI

1000-324X

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