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rGO-Fe3O4活化过硫酸盐处理酸性红73

尹飞 王翠 童少平

化工学报2019,Vol.70Issue(1):207-213,7.
化工学报2019,Vol.70Issue(1):207-213,7.DOI:10.11949/j.issn.0438⁃1157.20180918

rGO-Fe3O4活化过硫酸盐处理酸性红73

Treatment of acid red 73 by persulfate in the presence of rGO-Fe3O4 composite

尹飞 1王翠 1童少平1

作者信息

  • 1. 浙江工业大学化学工程学院,绿色化学合成技术国家重点实验室培育基地,浙江杭州310032
  • 折叠

摘要

Abstract

A reduced graphene oxide nanosheet-iron oxide composite (rGO-Fe3O4) was synthesized by using coprecipitation method, and characterized by using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). The rGO-Fe3O4 composite was used as heterogeneous catalyst to activate persulfate (PS) to decolor acid red 73 (AR73). The effects of catalyst dosage, PS concentration, initial pH value and reaction temperature on the decolorization efficiency were investigated. The results showed that 50 mg/L AR73 was totally removed in 10 min at room temperature when the concentrations of rGO-Fe3O4 and PS were both 1.0 g/L. Singlet oxygen was confirmed to be the primary reactive oxygen species by quenching experiment. This study shows that the rGO-Fe3O4 composite is a promising catalyst for activating PS to treat wastewater due to its high activity and easy separation.

关键词

还原石墨烯/四氧化三铁/高级氧化/单线态氧/过硫酸钠

Key words

reduced graphene/magnetite/advanced oxidation processes/singlet oxygen/persulfate

分类

资源环境

引用本文复制引用

尹飞,王翠,童少平..rGO-Fe3O4活化过硫酸盐处理酸性红73[J].化工学报,2019,70(1):207-213,7.

基金项目

国家自然科学基金项目(21176225) (21176225)

化工学报

OA北大核心CSCDCSTPCD

0438-1157

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