电源技术2019，Vol.43Issue(4)：583-586,4.
电纺Fe/N/C纳米纤维催化剂及其氧还原性能
Electrospun Fe/N/C nanofibers for oxygen reduction reaction in acidic media
摘要
Abstract
Fe/N/C catalyst is considered as a very promising catalyst for oxygen reduction reaction. To develop a facile mass production method, a series of Fe- and N-doped nano carbon fiber (Fe/N/C) catalysts were synthesized via electrospinning the mixture of poly(amic acid) (PAA) nanofiber-supported iron acetylacetonate [Fe(acac)3] and melamine. The composition and microstructural properties of prepared catalysts were identified by several characterization techniques including XRD, XPS,BET, SEM and TEM. The influence of the Fe loading on the performance of ORR was also investigated electrochemically in acid media. The onset and half-wave potential for Fe/N/CNFs-3 (3％ Fe) catalyst are just 34 and 120 mV lower than those of the commercial Pt/C catalyst, respectively. Moreover, the prepared catalyst exhibits comparable durability with the Pt/C catalyst during potential cycle testing.关键词
静电纺丝/纳米纤维/氧还原反应/质子交换膜燃料电池Key words
electrospinning/nanofiber/oxygen reduction reaction/PEMFC分类
信息技术与安全科学引用本文复制引用
王中伟,王敏,韦露,李建伟,赵新生..电纺Fe/N/C纳米纤维催化剂及其氧还原性能[J].电源技术,2019,43(4):583-586,4.基金项目
国家自然科学基金(21776119,21376113) （21776119,21376113）
江苏师范大学研究生科研创新计划项目(2016YYB072) （2016YYB072）
