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环保绝缘气体七氟异丁腈(C4F7N)的制备技术现状与发展

罗运柏 高占阳 高克利 刘伟 周文俊 王宝山

高电压技术2019,Vol.45Issue(4):1009-1017,9.
高电压技术2019,Vol.45Issue(4):1009-1017,9.DOI:10.13336/j.1003-6520.hve.20190329001

环保绝缘气体七氟异丁腈(C4F7N)的制备技术现状与发展

Current Status and Development of Preparation Technology of Environment Friendly Insulating Gas Heptafluoroisobutyronitrile (C4F7N)

罗运柏 1高占阳 1高克利 2刘伟 3周文俊 4王宝山1

作者信息

  • 1. 武汉大学化学与分子科学学院有机硅化合物及材料教育部工程研究中心, 武汉 430072
  • 2. 中国电力科学研究院有限公司, 北京 100192
  • 3. 国网安徽省电力有限公司电力科学研究院, 合肥 230022
  • 4. 武汉大学电气与自动化学院, 武汉 430072
  • 折叠

摘要

Abstract

Heptafluoroisobutyronitrile is considered to be an attractive alternative gas of SF6 because of its excellent insulating properties and low GWP. However, heptafluoroisobutyronitrile has not been industrially produced, and the preparation technology is the crucial problem that restricts its large-scale application. In order to break through the international barriers and accelerate the process of localization, the preparation technology of heptafluoroisobutyronitrile at home and abroad is reviewed and the research of traditional and new progress is introduced in detail with the reaction process of various method described. From the angle of the comparison of raw material toxicity, reaction conditions, reaction equipment and product yield, the preparation methods with industrial production potential are proposed, and the development of preparation technology of heptalfluoroisobutyronitrile is prospected.

关键词

六氟化硫/七氟异丁腈/绝缘气体/温室效应/工业制备/毒性/产率

Key words

sulfur hexafluoride/heptafluoroisobutyronitrile/insulation gas/greenhouse effect/industrial preparation/toxicity/yield

引用本文复制引用

罗运柏,高占阳,高克利,刘伟,周文俊,王宝山..环保绝缘气体七氟异丁腈(C4F7N)的制备技术现状与发展[J].高电压技术,2019,45(4):1009-1017,9.

基金项目

国家重点研发计划 (2017YFB0902500) (2017YFB0902500)

国家电网公司总部科技项目 (环保型管道输电关键技术) (环保型管道输电关键技术)

武汉大学博士研究生学分课程建设项目 ()

高电压技术

OA北大核心CSCDCSTPCD

1003-6520

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