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氧化改性木质素磺酸钠-石墨烯复合量子点的制备及性能

许利娜 杨小华 丁海阳 李梅 夏建陵

林产化学与工业2019,Vol.39Issue(1):29-34,6.
林产化学与工业2019,Vol.39Issue(1):29-34,6.DOI:10.3969/j.issn.0253-2417.2019.01.004

氧化改性木质素磺酸钠-石墨烯复合量子点的制备及性能

Synthesis and Properties of Oxidative Modified Satium Lignosulfonate/ Graphene Quantum Dots Composites

许利娜 1杨小华 2丁海阳 1李梅 2夏建陵1

作者信息

  • 1. 中国林业科学研究院 林产化学工业研究所
  • 2. 生物质化学利用国家工程实验室,国家林业局林产化学工程重点开放性实验室,江苏省 生物质能源与材料重点实验室,江苏 南京 210042
  • 折叠

摘要

Abstract

Oxidative modified sodium lignosulfonate/graphene quantum dots (HSL/GQDs) composites was synthesized using by products of the sulfite-pulping procedure (sodium lignosulfonate) and citric acid.Fluorescence spectroscopy, UV-vis spectra, and TEM were used to investigate the optical properties, structure and ions detection of the prepared HSL/GQDs.The HSL/GQDs exhibited strong fluorescence, which present two times high intensity (F0) than that of the free GQDs. The experimental results showed that HSL/GQDs could detect Fe3+ with high sensitivity and specificity according to the change of the fluorescence intensity. The Fe3+ concentration and the fluorescent quenching intensity of prepared HSL/GQD safter adding Fe3+ presented a good linearity in range of 10-500 μmol/L, with alinear equation of F/F0=0.851 12-0.001 11C (Fe3+) (R2=0.99) .

关键词

氧化改性木质素磺酸钠/石墨烯量子点/荧光探针/Fe3+

Key words

oxidative modification lignin/graphene quantum dots/fluorescent sensor/Fe3+

分类

化学化工

引用本文复制引用

许利娜,杨小华,丁海阳,李梅,夏建陵..氧化改性木质素磺酸钠-石墨烯复合量子点的制备及性能[J].林产化学与工业,2019,39(1):29-34,6.

基金项目

中央级公益性科研院所基本科研业务费专项资金(CAFYBB2017QA016) (CAFYBB2017QA016)

林产化学与工业

OA北大核心CSCDCSTPCD

0253-2417

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