聊城大学学报（自然科学版）2018，Vol.31Issue(4)：94-98,5.DOI:10.19728/j.issn1672-6634.2018.04.016
一个由双核{Cd2}簇构成的一维链状配位聚合物的合成、结构及荧光性质研究
Synthesis, Structure and Luminescent Property of A 1D Chain Coordination Polymer Constructed by{Cd2}Clusters as SBUs
摘要
Abstract
A novel coordination polymer, [Cd (Hbtpca) (Me2-2, 2′-bipy) ]n (1) (H3 btpca=1, 1′, 1″- (benzene-1, 3, 5-triyl) tripiperidine-4-carboxylic acid;Me2-2, 2′-bipy=4, 4′-Dimethyl-2, 2′-bipyridyl), has been synthesized by reaction of Cd (NO3) 2·4 H2 O, H3 btpca, and Me2-2, 2′-bipy under solvothermal synthesis condition.Structural analysis reveals that two adjacent Cd (Ⅱ) ions are bridged by two Hbtpca2-ligands to form a dinuclear{Cd2}cluster as SBU (secondary building unit), which are further linked by Hbtpca2-ligands to yield a 1 Dchain structure.Compound (1) was characterized by elemental analysis, IR (infrared spectroscopy), as well as powder and single-crystal X-ray diffraction analysis.Moreover, the solid-stage photoluminescence properties of (1) have been well investigated.关键词
配位聚合物/溶剂热合成/晶体结构/荧光性质Key words
coordination polymer/solvothermal synthesis/crystal structure/photoluminescence properties分类
化学化工引用本文复制引用
马惠彦,张文洁,杨娜,李梦瑶,马晓红,李允伍..一个由双核{Cd2}簇构成的一维链状配位聚合物的合成、结构及荧光性质研究[J].聊城大学学报（自然科学版）,2018,31(4):94-98,5.基金项目
国家自然科学基金项目 (21771095) （21771095）
山东省属高校优秀青年人才联合基金 (ZR2017JL013) 资助 （ZR2017JL013）
