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D001型阳离子交换树脂吸附Cr(Ⅲ)的平衡特性及动力学

张学峰 谈定生 谢昀映 李增辉 丁伟中

湿法冶金2019,Vol.38Issue(1):16-21,6.
湿法冶金2019,Vol.38Issue(1):16-21,6.DOI:10.13355/j.cnki.sfyj.2019.01.004

D001型阳离子交换树脂吸附Cr(Ⅲ)的平衡特性及动力学

Equilibrium Behaviour and Kinetics of Adsorption Cr (Ⅲ) onto Cation Exchange Resin D001

张学峰 1谈定生 1谢昀映 2李增辉 1丁伟中1

作者信息

  • 1. 上海大学 材料科学与工程学院, 上海 200444
  • 2. 上海大学省部共建高品质特殊钢冶金与制备国家重点实验室, 上海 200444
  • 折叠

摘要

Abstract

Adsorption of Cr (Ⅲ) from wastewater using cation exchange resin D001 was reseached.The thermodynamics and kinetics of adsorption process were investigated.The results show that the Redlich Peterson model can use to describe the adsorption process.The thermodynamics parameters indicate that the adsorption process is spontaneous, endothermic and adding entropy.The adsorption rate follows the pseudo-second-order kinetics model with the activation energy of 27.45kJ/mol.The kinetics experiment results show the intraparticle diffusion is the adsorption process rate-limiting step.

关键词

离子交换/Cr(Ⅲ)/吸附/热力学/动力学

Key words

ion exchange/Cr (Ⅲ)/adsorption/thermodynamics/kinetics

分类

能源科技

引用本文复制引用

张学峰,谈定生,谢昀映,李增辉,丁伟中..D001型阳离子交换树脂吸附Cr(Ⅲ)的平衡特性及动力学[J].湿法冶金,2019,38(1):16-21,6.

湿法冶金

OA北大核心

1009-2617

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