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聚丙烯腈纳米纤维增强聚氨酯基复合膜的制备及其力学性能的研究

王鑫 赵莹 李妮

现代纺织技术2019,Vol.27Issue(2):12-17,6.
现代纺织技术2019,Vol.27Issue(2):12-17,6.DOI:10.19398/j.att.201709036

聚丙烯腈纳米纤维增强聚氨酯基复合膜的制备及其力学性能的研究

Study on the Preparation of Polyurethane-based Composite Film Reinforced with Polyacrylonitrile Nanofiber and Its Mechanical Properties

王鑫 1赵莹 2李妮1

作者信息

  • 1. 浙江理工大学 丝绸学院、材料与纺织学院, 杭州 310018
  • 2. 浙江理工大学 先进纺织材料与制备技术教育部重点实验室, 杭州 310018
  • 折叠

摘要

Abstract

Polyacrylonitrile/polyurethane (PAN/PU) composite nanofiber film was prepared by electrospinning. Then polyurethane-based composite film reinforced with polyacrylonitrile nanofiber (PANNFs/PU) was prepared by heating PAN/PU nanofibrous film. The morphological structure of PAN/PU film before and after heat treatment was analyzed by scanning electron microscope (SEM). The mechanical properties of films were tested by multi-function stretcher. The results showed that the mechanical properties of PANNFs/PU film were influenced by the one occupying a large ratio in the electrospun solution. When the mass ratio of PAN and PU in the electrospun solution was 4:6, the breaking stress of prepared PANNFs/PU film reached 152.1 MPa, and the breaking elongation reached 178.8%. Compared with other mass ratio, PANNFs/PU composite film showed the better overall mechanical properties under the mass ratio of 4∶6. When the quality ratio was 4∶6 and the mass fraction of electrospun solution increased to 18%, the breaking stress of PANNFs/PU composite film increased by about 3 times (up to 217.8 MPa) and the breaking elongation increased by about 2.5 times (up to 320.9%) compared with PAN/PU composite nanofiber film.

关键词

纳米纤维/聚丙烯腈/聚氨酯/复合膜

Key words

nanofibers/polyacrylonitrile/polyurethane/composite film

分类

轻工纺织

引用本文复制引用

王鑫,赵莹,李妮..聚丙烯腈纳米纤维增强聚氨酯基复合膜的制备及其力学性能的研究[J].现代纺织技术,2019,27(2):12-17,6.

现代纺织技术

OACSTPCD

1009-265X

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