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负载1-丁基-3-甲基咪唑氯的固体炭磺酸催化水解纤维素

屈浩楠 暴冲 马文静 马一鸣 赵鹏 王新海 周艳梅

应用化学2019,Vol.36Issue(1):58-64,7.
应用化学2019,Vol.36Issue(1):58-64,7.DOI:10.11944/j.issn.1000-0518.2019.01.180049

负载1-丁基-3-甲基咪唑氯的固体炭磺酸催化水解纤维素

Hydrolysis of Cellulose by Solid Carbon Sulfonic Acid Supported 1-Butyl-3-methylimidazolium Chloride

屈浩楠 1暴冲 1马文静 1马一鸣 1赵鹏 1王新海 1周艳梅1

作者信息

  • 1. 河南大学化学化工学院,河南省环境污染控制材料国际联合实验室,河南开封 475004
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摘要

Abstract

Cellulose is a renewable resource. Compounds obtained by the hydrolysis of cellulose are of great significance to ease the energy pressure. Herein, the hydrolysis of cellulose catalyzed by solid carbon sulfonic acid supported 1-butyl-3-methylimidazolium chloride is reported. The solid carbon sulfonic acid obtained from bamboo biomass by pre-carbonization at 700 ℃ and sulfonation at 150 ℃ was used as the matrix. Ionic liquid functionalized solid carbon sulfonic acid catalyst was obtained by loading 1-butyl-3-methylimidazolium chloride. The results show that the total reducing sugar yield under optimal conditions is increased by 15. 2%relative to the total reducing sugar yield by exploiting solid carbon sulfonic acid. The catalyst still exhibits good performance after recycling.

关键词

固体炭磺酸/离子液体/水解纤维素

Key words

solid carbon sulfonic acid/ionic liquids/hydrolysis of cellulose

分类

化学化工

引用本文复制引用

屈浩楠,暴冲,马文静,马一鸣,赵鹏,王新海,周艳梅..负载1-丁基-3-甲基咪唑氯的固体炭磺酸催化水解纤维素[J].应用化学,2019,36(1):58-64,7.

基金项目

国家自然科学基金 (21576071, 21776061) 资助 (21576071, 21776061)

应用化学

OA北大核心CSCDCSTPCD

1000-0518

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