应用化学2019，Vol.36Issue(1)：120-122,3.DOI:10.11944/j.issn.1000-0518.2019.01.180212
臭氧化合成聚乙二醇醛基衍生物
Synthesis of Polyethylene Glycol Aldehyde Derivatives by Ozonation
摘要
Abstract
Methoxypolyethylene glycol olefin was obtained by olefination of methoxypolyethylene glycol, and followed by ozonation to give methoxypolyethylene glycol aldehyde derivative. The properties of products were characterized by nuclear magnetic resonance spectroscopy (NMR) and matrix-assisted laser desorption/ionization time of flight mass spectrometry (MALDI-TOF-MS) . The results show that the product has high purity and no by-products. The yields of methoxy polyethylene glycol acetaldehyde and polyethylene glycol propionaldehyde are as high as 98％ and 99％, respectively, and the degrees of substitution are 90. 87％ ～99. 91％ and 98％ ～ 100％, respectively.关键词
聚乙二醇/臭氧化/醛基Key words
polyethylene glycol/ozonation/aldehyde分类
化学化工引用本文复制引用
吕文强,耿超,徐经伟..臭氧化合成聚乙二醇醛基衍生物[J].应用化学,2019,36(1):120-122,3.基金项目
国家自然科学基金 (61504145) 资助项目 （61504145）
