化工学报2019，Vol.70Issue(6)：2092-2101,10.DOI:10.11949/0438⁃1157.20190028
莰烯+(+)-3-蒈烯体系汽液平衡数据的测定与关联
Determination and correlation of vapor-liquid equilibrium data for camphene+(+)-3-carene system
摘要
Abstract
The insulation, stirring and pressure control system of Ellis equilibrium still with double circulator for the vapor and liquid phases was improved, and a set of phase equilibrium experimental device with visual window was established. The vapor-liquid equilibrium data of terpene+(+)-3-decene system at 313.15, 373.15 and 433.15 K were determined. The thermodynamic consistency test was performed on the experimental data by area method and Van Ness test. All data were consistent with Gibbs-Duhenm. Furthermore, the VLE data were correlated by the nonrandom two-liquid (NRTL), Wilson and universal quasichemical (UNIQUAC) activity coefficient models in Aspen plus. The objective function was optimized by the maximum likelihood method and the corresponding binary interaction parameters were returned. The results show that the maximum average relative deviation between calculated values and experimental data of the vapor phase molar composition and equilibrium pressure was 0.0128 and 0.0009, the maximum root mean square deviations are 0.0003 and 0.0012 kPa, and the absolute average deviations of relative volatility are 0.09%, 0.03% and 0.04%, respectively.关键词
莰烯/(+)-3-蒈烯/Ellis平衡釜/等温汽液平衡/测定/关联Key words
camphene/(+)-3-carene/Ellis equilibrium still/isothermal vapor-liquid equilibrium/determination/correlation分类
化学化工引用本文复制引用
吴金芝,王琳琳,陈小鹏,童张法,范孝雄,梁保芳..莰烯+(+)-3-蒈烯体系汽液平衡数据的测定与关联[J].化工学报,2019,70(6):2092-2101,10.基金项目
国家自然科学基金项目(21878025,21776069,21476070) （21878025,21776069,21476070）
