石油化工2019，Vol.48Issue(9)：963-967,5.DOI:10.3969/j.issn.1000-8144.2019.09.014
罗丹明席夫碱荧光探针的合成及在Cu2+和Fe3+检测中的应用
Synthesis of rhodamine schiff base fluorescent probe and application thereof in detection of Cu2+ and Fe3+
摘要
Abstract
A rhodamine schiff base fluorescent probe(RBr) was prepared by condensing rhodamine hydrazide with p-bromobenzaldehyde. Its structure was characterized by single crystal XRD and NMR spectroscopy. In aqueous acetonitrile solution,RBr exhibited significant absorbance and fluorescence selectivity for Cu2+ and Fe3+,and there was a good linear relationship between the spectral intensity and ion concentration. The Job’s Plot experiment confirmed that the spirolactam structure of RBr was induced to open upon the coordination of Cu2+/Fe3+,and a 1∶1 metal-probe complex was formed. The absorption intensity of RBr-Cu2+ solution was enhanced under the irradiation of ultraviolet light.关键词
罗丹明探针/铜离子/铁离子/紫外光检测Key words
rhodamine probe/copper ion/iron ion/ultraviolet detection分类
化学化工引用本文复制引用
郭振丽,杨杨,刘景林,许良..罗丹明席夫碱荧光探针的合成及在Cu2+和Fe3+检测中的应用[J].石油化工,2019,48(9):963-967,5.基金项目
国家自然科学基金项目(21362020) （21362020）
内蒙古自治区自然科学基金面上项目(2015MS0223) （2015MS0223）
内蒙古自治区高等学校科学研究项目(NJZZ19146) （NJZZ19146）
内蒙古自治区纳米碳材料重点实验室开放课题(MDK2019011) （MDK2019011）
内蒙古民族大学研究生科研立项(NMDSS1933). （NMDSS1933）
