化工学报2019，Vol.70Issue(z2)：62-69,8.DOI:10.11949/0438-1157.20190592
气体在混合溶液中溶解度的分子热力学计算
Molecular thermodynamics for solubility of gas in binary liquid
摘要
Abstract
A molecular-thermodynamic theory has been developed for predicting the solubility of a sparingly soluble gas in a complex binary liquid mixture at 0.101325 MPa. The binary liquid mixtures contain associating and solvating components whose molecules form weak chemical compounds. The Gibbs energy for the mixing process is the sum of three isothermal steps. The partial molar excess Gibbs energy of the solute is represented by two contributions, chemical and physical. When experimental uncertainties are taken into account, the predicted solubility of nitrogen in the binary solvent is in good agreement with previously published experimental solubility data.关键词
热力学/溶解性/相平衡Key words
thermodynamics/ solubility/ phase equilibria分类
能源科技引用本文复制引用
杨富鑫,王晓坡,陈强,谭厚章..气体在混合溶液中溶解度的分子热力学计算[J].化工学报,2019,70(z2):62-69,8.基金项目
国家自然科学基金项目(51606147) （51606147）
