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金属有机框架光催化剂微环境调控研究进展

安珂 杨冬 赵展烽 任汉杰 陈瑶 周致远 姜忠义

化工学报2019,Vol.70Issue(10):3776-3790,15.
化工学报2019,Vol.70Issue(10):3776-3790,15.DOI:10.11949/0438-1157.20190601

金属有机框架光催化剂微环境调控研究进展

Research progress on microenvironment regulation of metal-organic framework photocatalyst

安珂 1杨冬 2赵展烽 3任汉杰 4陈瑶 1周致远 2姜忠义1

作者信息

  • 1. 天津大学化工学院绿色化学化工教育部重点实验室,天津300072
  • 2. 天津化学化工协同创新中心,天津300072
  • 3. 天津大学化工学院系统生物工程教育部重点实验室,天津300072
  • 4. 天津大学环境科学与工程学院,天津300072
  • 折叠

摘要

Abstract

Metal organic framework materials (MOFs) are a class of inorganic metal centers and organic ligands formed by self-assembly of crystalline porous materials. MOFs combine high crystallinity and electron mobility of inorganic materials with high specific surface area, porosity and modifiability of organic materials, thus exhibiting broad application prospects in the field of photocatalysis. The research on MOFs photocatalytic materials in recent years is reviewed centering on the regulation of physical and chemical microenvironment. The regulation of physical microenvironment has been focused on micromorphology regulation, noble metal deposition and heterostructure construction, meanwhile the regulation of chemical microenvironment has been focused on metal site regulation and organic ligand regulation. In addition, in order to provide ideas for rational design and controllable preparation of high-performance MOF photocatalysts, the future development of MOF photocatalytic materials is also prospected.

关键词

金属有机框架材料/微环境/催化剂/光化学/太阳能

Key words

metal-organic frameworks/microenvironment/catalyst/photochemistry/solar energy

分类

化学化工

引用本文复制引用

安珂,杨冬,赵展烽,任汉杰,陈瑶,周致远,姜忠义..金属有机框架光催化剂微环境调控研究进展[J].化工学报,2019,70(10):3776-3790,15.

基金项目

国家自然科学基金创新研究群体项目(21621004,91534126) (21621004,91534126)

天津市自然科学基金面上项目(18JCYBJC21000) (18JCYBJC21000)

化工学报

OA北大核心CSCDCSTPCD

0438-1157

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