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Pt-WO3纳米片的合成及其电催化析氢性能研究

蒋鹏杰 吕燚 陈昌淼 何宏程 蔡勇 张明

电化学2019,Vol.25Issue(5):562-570,9.
电化学2019,Vol.25Issue(5):562-570,9.DOI:10.13208/j.electrochem.181143

Pt-WO3纳米片的合成及其电催化析氢性能研究

A Facile Route to Synthesize Pt-WO3 Nanosheets with Enhanced Electrochemical Performance for HER

蒋鹏杰 1吕燚 1陈昌淼 1何宏程 1蔡勇 1张明1

作者信息

  • 1. 湖南大学物理与微电子科学学院,微纳光电器件及应用教育部重点实验室,材料科学与工程学院,湖南长沙410082
  • 折叠

摘要

Abstract

Platinum-tungsten trioxide (Pt-WO3) nanosheets were synthesized on nickel foams (NFs) directly.As great conductive networks,NFs substrates could greatly improve the electrode performance of WO3.The modified platinum nanoparticles not only enhanced the electron transformation of catalysts,but also increased the active sites for hydrogen evolution reaction (HER).Pt-WO3/NF revealed a better catalytic activity than WO3/NFs with a smaller Tafel slope (80 mV· dec-1) and a lower overpotential of 72 mV at the current density of 10 mA· cm-2.In addition,Pt-WO3/NF showed great durability and stability during the long-term electrochemical test of 45 h.This work provides a facile strategy of improving transition metal oxides (TMOs) as high activity HER catalysts for promising practical applications.

关键词

氧化钨/析氢反应/纳米片/铂催化剂

Key words

tungsten oxide/hydrogen evolution reaction/nanosheets/platinum catalysts

分类

化学化工

引用本文复制引用

蒋鹏杰,吕燚,陈昌淼,何宏程,蔡勇,张明..Pt-WO3纳米片的合成及其电催化析氢性能研究[J].电化学,2019,25(5):562-570,9.

基金项目

This work is supported by National Natural Science Foundation of China (51772082,51574117,and 51804106) and China Postdoctoral Science Foundation (2017M6140495,2018T10822). (51772082,51574117,and 51804106)

电化学

OA北大核心CSCDCSTPCD

1006-3471

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