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纳米碳管改善氧化铝填充硅橡胶复合材料的导热与机械性能

林嘉隆 苏诗茗 贺艳兵 康飞宇

新型炭材料2020,Vol.35Issue(1):66-72,7.
新型炭材料2020,Vol.35Issue(1):66-72,7.DOI:10.1016/S1872-5805(20)60476-0

纳米碳管改善氧化铝填充硅橡胶复合材料的导热与机械性能

Improving the thermal and mechanical properties of an alumina-filled silicone rubber composite by incorporating carbon nanotubes

林嘉隆 1苏诗茗 2贺艳兵 1康飞宇1

作者信息

  • 1. 清华大学深圳国际研究生院 炭功能材料工程实验室,广东 深圳 518055
  • 2. 清华大学 材料学院先进材料教育部重点实验室,北京 100084
  • 折叠

摘要

Abstract

Carbon nanotubes ( CNTs) can be used to improve the thermal and mechanical properties of composites because of their excellent characteristics. Methyl vinyl silicone rubber matrix composites filled with alumina ( Al2 O3 ) powder and CNTs were fabricated by a conventional mechanical blending method. The effects of the mass fraction of Al2 O3 powder, surface modification of Al2 O3 powder by silanization with dodecyltrimethoxysilane and the addition of CNTs on the thermal conductivity, Young's modulus and hardness of the composites were investigated. Results showed that a higher mass fraction of Al2 O3 powder results in a higher thermal conductivity of the composites. When the mass fraction of Al2 O3 powder was fixed, the thermal conductivity, Young’s modulus and hardness of the composites were obviously improved by surface modification of the powder and adding a small amount of CNTs. A combination of the modified Al2 O3 filler and CNT filler improves the interfacial interaction between the fillers and rub-ber matrix by the formation of better heat conduction channels and network structures in the rubber matrix, thereby improving the thermal conductivity and mechanical properties of the composites.

关键词

纳米碳管/氧化铝/硅橡胶/热导率/协同效应

Key words

Carbon nanotubes/ Alumina/ Silicone rubber/ Thermal conductivity/ Synergistic effect

分类

通用工业技术

引用本文复制引用

林嘉隆,苏诗茗,贺艳兵,康飞宇..纳米碳管改善氧化铝填充硅橡胶复合材料的导热与机械性能[J].新型炭材料,2020,35(1):66-72,7.

基金项目

国家自然科学基金(51672156). National Natural Science Foundation of China (51672156). (51672156)

新型炭材料

OA北大核心CSCDCSTPCDSCI

1007-8827

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