电化学2020，Vol.26Issue(1)：41-53,13.DOI:10.13208/j.electrochem.181242
铜电极上二氧化碳还原机理的研究进展
Recent Progress in the Mechanistic Understanding of CO2 Reduction on Copper
摘要
Abstract
In this review,we present the major developments in the understanding of the mechanisms of the electrochemical reduction of CO2 from a historical perspective.Most of the work discussed in this review was carried out at copper electrodes,as this is the only material at which hydrocarbons are produced in reasonable quantities.The emphasis focuses on the differentiation of mechanisms for the generation of C1 and C2 products as well as factors and methods for controlling the product selectivity of CO2 reduction.We have highlighted ambiguities,assumptions,and important methodologies,such as differential electrochemical mass spectrometry and electrochemical in-situ infrared spectroscopy,which help greatly to clarify these issues in the literature.关键词
二氧化碳还原/反应机理/红外光谱/微分电化学质谱/铜电极Key words
CO2 reduction/mechanism/infrared spectroscopy/differential electrochemical mass spectrometry/Cu electrode分类
化学化工引用本文复制引用
Matthew M Sartin,陈微,贺凡,陈艳霞..铜电极上二氧化碳还原机理的研究进展[J].电化学,2020,26(1):41-53,13.基金项目
This work was supported by the Natural Science Foundation of China(No.91545124,No.21750110437).MMS is supported by the Chinese Academy of Sciences President's International Fellowship Initiative (Grant No.2017PM0049). （No.91545124,No.21750110437）
