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Z型BiVO4/GO/g-C3N4复合材料的制备及其可见光下催化性能

许世超 朱天哲 乔阳 白学健 唐楠 郑春明

无机材料学报2020,Vol.35Issue(7):839-846,8.
无机材料学报2020,Vol.35Issue(7):839-846,8.DOI:10.15541/jim20190380

Z型BiVO4/GO/g-C3N4复合材料的制备及其可见光下催化性能

Fabrication of Z-scheme BiVO4/GO/g-C3N4 Photocatalyst with Efficient Visble-light Photocatalytic Performance

许世超 1朱天哲 1乔阳 2白学健 2唐楠 1郑春明2

作者信息

  • 1. 天津工业大学 环境科学与工程学院,天津 300389
  • 2. 天津工业大学 化学化工学院,天津 300389
  • 折叠

摘要

Abstract

Fabricating Z-scheme photocatalysts is a promising method for improving photocatalytic activity by ef-fectively enhancing charge separation. A new Z-scheme BiVO4/GO/g-C3N4 photocatalyst was prepared by two steps of impregnation-calcination and hydrothermal method, and then characterized by different methods. In the photo-catalytic process of BiVO4/GO/g-C3N4, GO nanosheet act as fast transmission channels between BiVO4 and g-C3N4 and can suppress electron-hole recombination, which significantly promotes the charge separation and improves the redox ability of the ternary heterojunction. The ternary photocatalyst has good photocatalytic degradation of Rho-damine B (RhB) as compared to the single-component or binary composite. It is capable of degrading 85% of RhB in 120 min under visible light irradiation and the hole (h+) plays a major role in the reaction. This work provides a simple preparation method for a ternary photocatalyst system in which g-C3N4 coupled with BiVO4 by GO to sig-nificantly improve photocatalytic activity.

关键词

BiVO4/g-C3N4/GO/三元催化剂/Z型异质结

Key words

BiVO4/g-C3N4/GO/ternary photocatalyst/Z-scheme heterojunction

分类

通用工业技术

引用本文复制引用

许世超,朱天哲,乔阳,白学健,唐楠,郑春明..Z型BiVO4/GO/g-C3N4复合材料的制备及其可见光下催化性能[J].无机材料学报,2020,35(7):839-846,8.

基金项目

National Natural Science Foundation of China (51772208, 51678409) (51772208, 51678409)

Natural Science Foundation of Tianjin (17JCYBJC15900) (17JCYBJC15900)

无机材料学报

OA北大核心CSCDCSTPCDSCI

1000-324X

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