纳微快报（英文）2021，Vol.13Issue(1)：1-14,14.
Enhanced Potassium-Ion Storage of the 3D Carbon Superstructure by Manipulating the Nitrogen-Doped Species and Morphology
Enhanced Potassium?Ion Storage of the 3D Carbon Superstructure by Manipulating the Nitrogen?Doped Species and Morphology
摘要
Abstract
Potassium-ion batteries (PIBs) are attractive for gridscale energy storage due to the abundant potassium resource and high energy density. The key to achieving high-performance and large-scale energy storage technology lies in seeking eco-efficient synthetic processes to the design of suitable anode materials. Herein, a spherical sponge-like carbon superstructure (NCS) assembled by 2D nanosheets is rationally and efficiently designed for K+ storage. The optimized NCS electrode exhibits an outstanding rate capability, high reversible specific capacity (250 mAh g- 1 at 200 mA g-1 after 300 cycles), and promising cycling performance (205 mAh g-1 at 1000 mA g-1 after 2000 cycles). The superior performance can be attributed to the unique robust spherical structure and 3D electrical transfer network together with nitrogen-rich nanosheets. Moreover, the regulation of the nitrogen doping types and morphology of NCS-5 is also discussed in detail based on the experiments results and density functional theory calculations. This strategy for manipulating the structure and properties of 3D materials is expected to meet the grand challenges for advanced carbon materials as high-performance PIB anodes in practical applications.关键词
Polyimide/Nitrogen-doped/Potassium-ion battery/3D carbon materialKey words
Polyimide/Nitrogen-doped/Potassium-ion battery/3D carbon material引用本文复制引用
Yanhua Li,Xiaohua Chen,Kui Xiao,Cong Huang,Jin Wang,Ming Gao,Aiping Hu,Qunli Tang,Binbin Fan,Yali Xu..Enhanced Potassium-Ion Storage of the 3D Carbon Superstructure by Manipulating the Nitrogen-Doped Species and Morphology[J].纳微快报（英文）,2021,13(1):1-14,14.基金项目
The authors gratefully acknowledge financial support from the National Natural Science Foundation of China(Grant Nos.51772086,51572078,51872087,and 11605053),the Natural Science Foundation of Hunan Province(Grant No.2018JJ2038),and the Hunan Provincial Natural Science Foundation of China(Grant No.2017JJ3052).The manuscript was written through contributions of all authors.All authors have given approval to the final version of the manuscript. （Grant Nos.51772086,51572078,51872087,and 11605053）
