高等学校化学学报2021，Vol.42Issue(2)：333-348,16.DOI:10.7503/cjcu20200663
石墨炔孔结构:设计、合成和应用
Pore Structure of Graphdiyne:Design,Synthesis and Application
摘要
Abstract
As a new emerging carbon material,graphdiyne(GDY)presents abundant sub-nanoscale porous structure,special electronic properties,and can be achieved at relatively low temperature with a wet-chemical approach. Therefore,with those excellent properties,GDY has drawn great attentions in various research fields such as catalysis,energy conversion and storage. A prominent feature of GDY is its topologically ordered regular pore structures,while the bottom-up synthesis of GDY makes it structurally designable. In the past de?cade,a large number of experimental and theoretical researches have been carried out on its structure design , which reveals broad application prospects. Inspired by this,we systematically summarize the effects of mono?mers,catalysts,templates,and solvents on GDY's porous structures and discuss its corresponding applica?tions. We hope it will provide a guideline for the application-oriented design and synthesis of GDY with special pore structure. Finally,the challenges and opportunities brought by the design of porous structure of GDY are discussed,and the design of three-dimensional porous structure of GDY is prospected.关键词
石墨炔/孔结构设计/三维/合成/应用Key words
Graphdiyne/Pore structure design/Three dimensional/Synthesis/Application分类
化学化工引用本文复制引用
詹舒辉,赵亚松,杨乃亮,王丹..石墨炔孔结构:设计、合成和应用[J].高等学校化学学报,2021,42(2):333-348,16.基金项目
国家重点研发计划项目(批准号:2018YFA0703504)和国家自然科学基金(批准号:51932001, 21971244)资助.This work is supported by the National Key Research and Development Program of China (No.2018YFA0703504)and the National Natural Science Foundation of China(Nos.51932001,21971244). （批准号:2018YFA0703504）
