新型炭材料2021，Vol.36Issue(1)：93-105,13.DOI:10.1016/S1872-5805(21)60007-0
原位拉曼光谱在碱金属离子电池炭负极材料研究中的应用
The use of in-situ Raman spectroscopy in investigating carbon materials as anodes of alkali metal-ion batteries
摘要
Abstract
Raman spectroscopy is a fast, non-destructive and high-resolution characterization tool based on laser physics that can be applied to a wide range of materials science problems. It has proven to be an effective tool in studying phase transitions induced by variables such as temperature, pressure or electrochemical reactions. In-situ Raman spectroscopy can be used to track any micro-structural changes of the electrode materials and interface reactions in alkali metal-ion batteries during charging and discharging. Carbon materials have become the most widely used anode materials for lithium-ion batteries because of their good electrochemical reversibility, excellent stability, low electrochemical charge/discharge potential platform, and low cost. The use of in-situ Raman spectroscopy in understanding the reactions occurring in alkali metal-ion batteries using carbon anode materials is summarized with a focus on the energy storage mechanism in Li+/Na+/K+ion batteries using carbon materials such as graphite and hard carbon as the an-ode materials. The effects of size, stress, doping, and the solvation-assisted co-intercalation of Li+/Na+/K+ions on the energy storage behavior in alkali metal-ion batteries are analyzed. Based on the strength and weakness of in-situ Raman spectroscopy, its combina-tion with AFM, in situ XRD and other high-resolution in situ technologies is used to reveal the energy storage mechanisms.关键词
原位拉曼/炭负极材料/碱金属离子电池Key words
In situ Raman spectroscopy/Carbon materials/Alkali metal-ion battery分类
化学化工引用本文复制引用
程晓琴,李慧君,赵振新,王永祯,王晓敏..原位拉曼光谱在碱金属离子电池炭负极材料研究中的应用[J].新型炭材料,2021,36(1):93-105,13.基金项目
国家自然科学项目(U1810115,U1710256,52072256).The authors would like to offer special thanks to Naticnal Natural Science Foundation of China (U1810115, U1710256, 52072256). （U1810115,U1710256,52072256）
