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Defect and Doping Co-Engineered Non-Metal Nanocarbon ORR Electrocatalyst

Jian Zhang Jingjing Zhang Feng He Yijun Chen Jiawei Zhu Deli Wang Shichun Mu Hui Ying Yang

纳微快报(英文)2021,Vol.13Issue(4):178-207,30.
纳微快报(英文)2021,Vol.13Issue(4):178-207,30.

Defect and Doping Co-Engineered Non-Metal Nanocarbon ORR Electrocatalyst

Defect and Doping Co?Engineered Non?Metal Nanocarbon ORR Electrocatalyst

Jian Zhang 1Jingjing Zhang 2Feng He 1Yijun Chen 1Jiawei Zhu 1Deli Wang 3Shichun Mu 1Hui Ying Yang3

作者信息

  • 1. Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, People's Republic of China
  • 2. Pillar of Engineering Product Development, Singapore University of Technology and Design, 8 Somapah Road, Singapore 487372, Singapore
  • 3. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070,People's Republic of China
  • 折叠

摘要

Abstract

Exploring low-cost and earth-abundant oxygen reduction reaction (ORR) electrocatalyst is essential for fuel cells and metal–air batteries. Among them, non-metal nanocarbon with multiple advantages of low cost, abundance, high conductivity, good durability, and competi-tive activity has attracted intense interest in recent years. The enhanced ORR activities of the nanocarbons are normally thought to originate from heteroatom (e.g., N, B, P, or S) doping or various induced defects. How-ever, in practice, carbon-based materials usually contain both dopants and defects. In this regard, in terms of the co-engineering of heteroatom doping and defect inducing, we present an overview of recent advances in developing non-metal carbon-based electrocatalysts for the ORR. The characteristics, ORR performance, and the related mechanism of these functionalized nanocarbons by heteroatom doping, defect inducing, and in particular their synergistic promotion effect are emphatically analyzed and discussed. Finally, the current issues and perspectives in developing carbon-based electrocatalysts from both of heteroatom doping and defect engineering are proposed. This review will be beneficial for the rationaldesign and manufacturing of highly efficient carbon-based materials for electrocatalysis.

关键词

Defect/Doping/Electrocatalyst/Oxygen reduction reaction/Non-metal nanocarbon

Key words

Defect/Doping/Electrocatalyst/Oxygen reduction reaction/Non-metal nanocarbon

引用本文复制引用

Jian Zhang,Jingjing Zhang,Feng He,Yijun Chen,Jiawei Zhu,Deli Wang,Shichun Mu,Hui Ying Yang..Defect and Doping Co-Engineered Non-Metal Nanocarbon ORR Electrocatalyst[J].纳微快报(英文),2021,13(4):178-207,30.

基金项目

This work was financially sponsored by the National Natural Science Foundation of China (51802104), Foundation of State Key Laboratory of Coal Combustion (FSKL-CCA2008), and State Key Laboratory of Advanced Technology for Materials Synthesis and Processing (Wuhan University of Technol-ogy) (2021-KF-4). (51802104)

纳微快报(英文)

OACSCDEISCI

2311-6706

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