纳微快报(英文)2021,Vol.13Issue(5):45-60,16.
Non-Magnetic Bimetallic MOF-Derived Porous Carbon-Wrapped -TiO2/ZrTiO4 Composites for Efficient Electromagnetic Wave Absorption
Non?Magnetic Bimetallic MOF?Derived Porous Carbon?Wrapped -TiO2/ZrTiO4 Composites for Efficient Electromagnetic Wave Absorption
摘要
Abstract
Modern communication technologies put forward higher requirements for electromagnetic wave (EMW) absorption materials. Metal–organic framework (MOF) derivatives have been widely concerned with its diverse advantages. To break the mindset of magnetic-derivative design, and make up the shortage of monome-tallic non-magnetic derivatives, we first try non-magnetic bimetallic MOFs derivatives to achieve efficient EMW absorption. The porous carbon-wrapped -TiO2/ZrTiO4 com-posites derived from PCN-415 (TiZr-MOFs) are qualified with a minimum reflection loss of ? 67.8 dB (2.16 mm, 13.0 GHz), and a maximum effective absorption bandwidth of 5.9 GHz (2.70 mm). Through in-depth discussions, the synergy of enhanced interfacial polarization and other attenuation mechanisms in the composites is revealed. Therefore, this work confirms the huge potentials of non-magnetic bimetallic MOFs derivatives in EMW absorption applications.关键词
Bimetallic metal–organic framework/PCN-415/MOF derivatives/TiO2/ZrTiO4/C composites/Electromagnetic wave absorptionKey words
Bimetallic metal–organic framework/PCN-415/MOF derivatives/TiO2/ZrTiO4/C composites/Electromagnetic wave absorption引用本文复制引用
Jing Qiao,Jiurong Liu,Xue Zhang,Chang Liu,Longfei Lyu,Yunfei Yang,Zhou Wang,Lili Wu,Wei Liu,Fenglong Wang..Non-Magnetic Bimetallic MOF-Derived Porous Carbon-Wrapped -TiO2/ZrTiO4 Composites for Efficient Electromagnetic Wave Absorption[J].纳微快报(英文),2021,13(5):45-60,16.基金项目
The authors acknowledge funding from the National Natural Science Foundation of China(Nos.51572157,21902085,and 51702188),Natural Science Foundation of Shan-dong Province(No.ZR2019QF012),Fundamental Research Funds for the Central Universities(No.2018JC036 and No.2018JC046),and Young Scholars Program of Shandong University(No.2018WLJH25). (Nos.51572157,21902085,and 51702188)