高等学校化学学报2021，Vol.42Issue(5)：1357-1376,20.DOI:10.7503/cjcu20210013
可充电镁电池负极改性策略
Strategies Concerning Anode Modification in Rechargeable Magnesium Batteries
摘要
Abstract
Rechargeable magnesium batteries(RMBs)are a promising candidate for the development of high-energy storage systems due to its superiorities of relatively high theoretical volumetric capacity ,high crustal abundance,low cost,especially environmental friendliness and safety. It is worth noting that the formation of a passivation film on the surface of magnesium(Mg) anode in most conventional electrolytes is an enormous obstacle,which leads to irreversible deposition/stripping behavior of Mg and thus limits the implementation of commercial RMBs. Researches focusing on electrolytes to tackle the obstacle have been in the bottleneck due to the restrictions of expensive price,complex synthesize process,low ionic conductivity,poor compatibility with cathodes and anodes simultaneously,etc. Facilitating modification of anode coming back to conventional electrolytes in RMBs is an alternatively promising avenue. This review summarizes recent studies concerning anode modification including alloy anode materials and formation of artificial interphase . Based on the analysis and comparison of previous researches,we propose conclusion and perspective for further development of RMBs.关键词
可充电镁电池/合金负极/人工界面/传统电解液Key words
Rechargeable magnesium battery/Alloy anode/Artificial interphase/Conventional electrolyte分类
化学化工引用本文复制引用
薛琳琳,吕瑞景,王澳轩,罗加严..可充电镁电池负极改性策略[J].高等学校化学学报,2021,42(5):1357-1376,20.基金项目
国家自然科学基金(批准号:51872196)、天津市自然科学基金(批准号:17JCJQJC44100)和国家创新人才博士后计划(批准号:BX20190232)资助.This paper is supported by the National Natural Science Foundation of China(No.51872196),the Natural Science Foundation of Tianjin,China(No.17JCJQJC44100)and the National Postdoctoral Program for Innovative Talents,China(No.BX20190232). （批准号:51872196）
