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CoNiO2/Ti3C2Tx复合材料的制备及其电化学性能

苏兴华 韩晨曦 张静 王振军

硅酸盐学报2021,Vol.49Issue(6):1033-1040,8.
硅酸盐学报2021,Vol.49Issue(6):1033-1040,8.DOI:10.14062/j.issn.0454-5648.20200754

CoNiO2/Ti3C2Tx复合材料的制备及其电化学性能

Preparation and Electrochemical Performance of CoNiO2/Ti3C2Tx Composites

苏兴华 1韩晨曦 1张静 1王振军1

作者信息

  • 1. 长安大学材料科学与工程学院,西安 710061
  • 折叠

摘要

Abstract

CoNiO2/Ti3C2Tx composite was prepared by a facile co-precipitation method and subsequent heat treatment. The as-prepared samples were characterized by scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, nitrogen adsorption?desorption measurement, cyclic voltammetry, galvanostatic charge?discharge and electrochemical impedance spectroscopy. The results demonstrate that CoNiO2/Ti3C2Tx composite with a CoNiO2:Ti3C2Tx mass ratio of 30:1 exhibits the optimum electrochemical performance. The specific capacitance of CoNiO2/Ti3C2Tx composite is 389 F/g at a current density of 1 A/g, which is approximately 6 times greater than that of Ti3C2Tx. CoNiO2/Ti3C2Tx composite has the specific capacitance of 309 F/g when the current density increases to 20 A/g, and shows a cycle stability with 82% capacitance retention after 1500 charge?discharge cycles at a current density of 10 A/g.

关键词

复合材料/电极/超级电容器/二维碳化钛

Key words

composites/electrodes/supercapacitors/two-dimensional titanium carbide

分类

通用工业技术

引用本文复制引用

苏兴华,韩晨曦,张静,王振军..CoNiO2/Ti3C2Tx复合材料的制备及其电化学性能[J].硅酸盐学报,2021,49(6):1033-1040,8.

基金项目

陕西省重点研发计划项目(2019GY-174). (2019GY-174)

硅酸盐学报

OA北大核心CSCDCSTPCD

0454-5648

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