新型炭材料2021，Vol.36Issue(4)：665-682,18.DOI:10.1016/S1872-5805(21)60072-0
炭负载铁系元素催化剂在氧还原反应中的应用研究进展
Recent advances in carbon-supported iron group electrocatalysts for the oxygen reduction reaction
摘要
Abstract
Metal-air batteries are emerging energy devices that have received worldwide attention. The oxygen reduction reaction (ORR) is the key electrochemical process of metal-air batteries. The sluggish nature of ORR kinetics and the high cost of Pt-based ORR catalysts have severely hindered their large-scale application. As earth-abundant elements, the iron group elements have a vari-ety of hybrid orbitals, and their incorporation into the carbon skeleton achieves good ORR catalytic activity, giving them great poten-tial for substituting for Pt-based catalysts. Here, their uses for ORR and the function of each active site in the ORR process are sum-marized. The relationship between the microstructure and performance of these catalysts may help us fully understand the role of iron group elements in ORR and provide basic insight into the design of cheap catalysts with outstanding ORR catalytic performance in the future.关键词
铁系元素/炭基催化剂/杂原子掺杂/氧还原反应/结构调控Key words
Iron series elements/Carbon electrocatalysts/Heteroatomic doping/Oxygen reduction reaction/Adjustment and control of structure分类
通用工业技术引用本文复制引用
李平,王焕磊..炭负载铁系元素催化剂在氧还原反应中的应用研究进展[J].新型炭材料,2021,36(4):665-682,18.基金项目
Shandong Provincial Natural Science Founda-tion, China (No.ZR2020ME038) （No.ZR2020ME038）
Shandong Provin-cial Key R&D Plan and the Public Welfare Special Program, China (No.2019GGX102038) （No.2019GGX102038）
Fundamental Research Funds for the Central Universities (No.201941010 and 201822008) （No.201941010 and 201822008）
Qingdao City Programs for Science and Technology Plan Projects (19-6-2-77-cg) （19-6-2-77-cg）
National Natural Science Foundation of China(No.21471139). 基金项目:山东省自然科学基金(ZR2020ME038) （No.21471139）
山东省重点研发计划(公益类科技攻关)(2019GGX102038) （公益类科技攻关）
中央高校基本科研业务费专项(201941010, 201822008) （201941010, 201822008）
青岛市应用基础研究计划项目(19-6-2-77-cg) （19-6-2-77-cg）
国家自然科学基金(21471139). （21471139）
