纳微快报（英文）2021，Vol.13Issue(10)：276-287,12.
All-Climate Aluminum-Ion Batteries Based on Binder-Free MOF-Derived -FeS2@C/CNT Cathode
All?Climate Aluminum?Ion Batteries Based on Binder?Free MOF?Derived -FeS2@C/CNT Cathode
摘要
Abstract
Aluminum-ion batteries (AIBs) are promising next-generation batteries systems because of their features of low cost and abundant aluminum resource. However, the inferior rate capacity and poor all-climate performance, especially the decayed capacity under low temperature, are still critical challenges toward high-specific-capacity AIBs. Herein, we report a binder-free and freestanding metal–organic framework-derived -FeS2@C/carbon nanotube -(FeS2@C/CNT) as a novel all-climate cathode in AIBs working under a wide temperature window between ?25 and 50 °C with exceptional flexibility. The resultant cathode not only drastically suppresses the side reaction and volumetric expansion with high capacity and long-term stability but also greatly enhances the kinetic process in AIBs with remarkable rate capacity (above 151 mAh -g?1 at 2 A -g?1) at room temperature. More importantly, to break the bottleneck of the inherently low capacity in graphitic material-based all-climateAIBs, the new hierarchical conductive composite -FeS2@C/CNT highly promotes the all-climate performance and delivers as high as 117 mAh -g?1 capac-ity even under ?25 °C. The well-designed metal sulfide electrode with remarkable performance paves a new way toward all-climate and flexible AIBs.关键词
Aluminum-ion battery/All-climate battery/Iron sulfide/Binder-free/High rate capacityKey words
Aluminum-ion battery/All-climate battery/Iron sulfide/Binder-free/High rate capacity引用本文复制引用
Yuxiang Hu,Hongjiao Huang,Deshuang Yu,Xinyi Wang,Linlin Li,Han Hu,Xiaobo Zhu,Shengjie Peng,Lianzhou Wang..All-Climate Aluminum-Ion Batteries Based on Binder-Free MOF-Derived -FeS2@C/CNT Cathode[J].纳微快报（英文）,2021,13(10):276-287,12.基金项目
The authors acknowledge the financial support for Australian Research Council through its Discovery and  （）
Linkage Programs.This work was performed in part at Australian Microscopy&Microanalysis Research Facility at the Centre for Microscopy and Microanalysis,the University of Queensland(UQ).The authors also acknowledge National Natural Science Foundation of China(51901100 and 51871119),Jiangsu Provincial Founds for Natural Science Foundation(BK20180015),China Postdoctoral Science Foundation(2018M640481 and 2019T120426),and Jiangsu Postdoctoral Research Fund(2019K003). （UQ）
