燃料化学学报2021，Vol.49Issue(8)：1173-1180,8.DOI:10.1016/S1872-5813(21)60126-3
Rh-BIPHEPHOS催化剂作用下的丁烯异构与氢甲酰化反应
Isomerization and hydroformylation of butenes under the catalysis of Rh-BIPHEPHOS
摘要
Abstract
The isomerization and hydroformylation of butene under the catalysis of Rh-BIPHEPHOS were investigated by varying the butene feed and reaction temperature. The results indicate that in the presence of syngas, with 1-butene as feed, more isomerization product (i.e. 2-butene) is detected in comparison with the hydroformylation products, whereas with 2butene as the feed, the hydroformylation is superior to isomerization. Due to the equilibrium limit between 1-butene and 2butene, the increase of temperature shows a great positive effect on the isomerization reaction. Furthermore, under the catalysis of Rh-BIPHEPHOS, more n-pentanal is always formed than i-pentanal, as the larger bite angle of BIPHEPHOS restricts the intermediate rearrangement in the formation of i-pentanal.关键词
氢甲酰化/铑/催化/丁烯/戊醛/异构化Key words
hydroformylation/rhodium/catalysis/butene/pentanal/isomerization分类
化学化工引用本文复制引用
姜伟丽,何利梅,黄斌,陈雅琪,周广林,周红军..Rh-BIPHEPHOS催化剂作用下的丁烯异构与氢甲酰化反应[J].燃料化学学报,2021,49(8):1173-1180,8.基金项目
The project was supported by the Scientific Research and Technological Development Project of CNPC(LH-17-08-53-02)and the Strategic Cooperation Technology Projects of CNPC and CUPB(ZLZX2020-04). （LH-17-08-53-02）
