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氧化石墨烯掺杂的电纺聚酰亚胺基石墨纳米纤维的导热性能

袁泽正 康飞宇 杜鸿达 陈威 时赟凯 褚晓东 黄正宏 干林 李佳 贺艳兵 李宝华

新型炭材料2021,Vol.36Issue(5):940-948,9.
新型炭材料2021,Vol.36Issue(5):940-948,9.DOI:10.1016/S1872-5805(21)60077-X

氧化石墨烯掺杂的电纺聚酰亚胺基石墨纳米纤维的导热性能

Thermal conductivity of graphite nanofibers electrospun from graphene oxide-doped polyimide

袁泽正 1康飞宇 2杜鸿达 3陈威 1时赟凯 2褚晓东 3黄正宏 1干林 2李佳 4贺艳兵 1李宝华1

作者信息

  • 1. 广东省热管理工程与材料重点实验室 碳功能材料国家地方联合工程实验室,广东 深圳 518055
  • 2. 清华大学深圳国际研究生院,材料研究院,深圳盖姆石墨烯研究中心,广东 深圳 518055
  • 3. 清华大学 材料学院,新型陶瓷与精细工艺国家重点实验室,北京 100084
  • 折叠

摘要

Abstract

Aromatic polyimide (PI)-based graphite nanofibers were obtained from the graphitization of graphene oxide (GO)-doped electrospun PI nanofibers. GO improves the PI molecular orientation, crystalline structure and thermal conductivity of the res-ulting nanofibers. The degree of PI molecular orientation in the nanofibers is increased by the GO during fiber preparation. This im-provement in molecular orientation produces an increase in the thermal conductivity of the graphite nanofibers, and the addition of only 0.1%GO has a significant effect. The GO not only affects the thermal conductivity, but improves the PI molecular orientation and its role as nucleation centers during graphitization. This approach and the resulting high thermal conductivity materials show great potential for practical applications.

关键词

石墨纳米纤维/聚酰亚胺/氧化石墨烯/热导率

Key words

Graphite nanofiber/Polyimide/Graphene/Thermal conductivity

分类

通用工业技术

引用本文复制引用

袁泽正,康飞宇,杜鸿达,陈威,时赟凯,褚晓东,黄正宏,干林,李佳,贺艳兵,李宝华..氧化石墨烯掺杂的电纺聚酰亚胺基石墨纳米纤维的导热性能[J].新型炭材料,2021,36(5):940-948,9.

基金项目

广东珠江人才计划本土创新研究团队项目(2017BT01N111)和广东省重点实验室项目(2020B1212060015).This work was supported by the Local Innovat-ive and Research Teams Project of Guangdong Pearl River Talents Program(2017BT01N111),and Guang-dong Key Laboratory Project(2020B1212060015). (2017BT01N111)

新型炭材料

OA北大核心CSCDCSTPCDSCI

1007-8827

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