燃料化学学报2021，Vol.49Issue(10)：1402-1411,10.DOI:10.1016/S1872-5813(21)60156-1
氮掺杂多孔炭负载镍纳米粒子对高温煤焦油的催化加氢转化
Nitrogen-doped porous carbon supported nickel nanoparticles as catalyst for catalytic hydroconversion of high-temperature coal tar
摘要
Abstract
A novel and highly active nitrogen-doped porous carbon-supported nickel catalyst Ni@N-PC was successfully developed by a thermolysis of nickel-based zeolitic imidazolate frameworks growing on both sides of graphitic carbon nitride and used for catalyzing hydroconversion of isopropanol soluble portion from ultrasonic extraction of high-temperature coal tar (ISPHTCT). The active nickel nanoparticles were mainly encapsulated on the top of carbon nanotubes and partially dispersed on the surface of carbon nanosheets. Naphthalen-1-ol was used as a model compound to investigate the catalytic hydroconversion activity under different reaction conditions and reveal the mechanism for catalytic hydroconversion. The ISPHTCT and catalytic hydroconversion products of ISPHTCT (ISPCHCP) were analyzed with gas chromatograph/mass spectrometer. The results show that 70％ of naphthalen-1-ol was converted at 160 ℃ and completely converted at 200 ℃ for 120 min, and the ISPHTCT was greatly upgraded. A total of 180 organic compounds including 33 nitrogen-containing organic compounds, 11 sulfur-containing organic compounds and 39 oxygenates were identified in ISPHTCT, while no obvious nitrogen-containing organic compounds, sulfur-containing organic compounds and oxygenates were detected in ISPCHCP, indicating the excellent performance of Ni@N-PC for heteroatom removal. All the alkenes, cyclenes and alkynes were saturated and the majority of arenes were converted to cyclanes by catalytic hydroconversion over Ni@N-PC, which exhibited high catalytic hydrogenation activity.关键词
高温煤焦油/催化加氢转化/烃类/催化剂Key words
high-temperature coal tar/catalytic hydroconversion/hydrocarbons/catalysts分类
化学化工引用本文复制引用
谢瑞伦,张侠,田誉娇,雷昭,曹恩德..氮掺杂多孔炭负载镍纳米粒子对高温煤焦油的催化加氢转化[J].燃料化学学报,2021,49(10):1402-1411,10.基金项目
The project was supported by Natural Science Foundation of Anhui Province(1708085QB33)and Key Program for International S&T Cooperation Projects of China(2017YFE0124300)..安徽省自然科学基金(1708085QB33)和中国国际科技创新合作重点专项(2017YFE0124300)资助 （1708085QB33）
