燃料化学学报2021，Vol.49Issue(10)：1421-1434,14.DOI:10.1016/S1872-5813(21)60127-5
沸石催化甘蔗渣裂解制备多壁碳纳米管
Catalytic pyrolysis of sugarcane bagasse by zeolite catalyst for the production of multi-walled carbon nanotubes
摘要
Abstract
Recently, the disposal of waste by beneficial and environmentally friendly methods has attracted great attention. In this work, we have studied the production of high-value carbon nanotubes (CNTs) which have remarkable applications by catalytic pyrolysis of sugarcane bagasse (SCB) as an agricultural waste using a two-stage process. Various reaction factors including the effects of zeolite types (HZSM-5, HMOR, and HY), pyrolysis temperatures (450?700 ℃), and SCB/ZSM-5 ratios (3?12) on SCB pyrolysis were investigated to generate CNTs from pyrolysis products. A Co-Mo/MgO catalyst was used for growing CNTs via the decomposition of pyrolysis products. The morphological structure and quality of CNTs were characterized using TEM and Raman spectroscopy, while the fresh Co-Mo/MgO catalyst was characterized by XRD and TPR analyses. The results showed that zeolite type, pyrolysis temperature, and SCB/ZSM-5 ratio had significant effects on the CNTs yield. The optimum carbon yield (24.9％) was achieved using the HZSM-5 catalyst at the pyrolysis temperature of 500 ℃ and with the SCB/ZSM-5 ratio of 6. TEM observations confirmed the growth of bamboo-like carbon nanotubes (BCNTs) and carbon nano-onions (CNOs) in different proportions according to the reaction parameters. Also, CNTs with the largest diameter distribution range (7?76 nm) were produced using the SCB/ZSM-5 ratio of 6. Raman spectra demonstrated the production of high-quality CNTs under all studied conditions.关键词
碳纳米管/Co-Mo/MgO/热解/甘蔗渣/ZSM-5沸石Key words
carbon nanotubes/Co-Mo/MgO/pyrolysis/sugarcane bagasse/ZSM-5 zeolite分类
化学化工引用本文复制引用
ABOUL-ENEIN Ateyya A.,AWADALLAH Ahmed E.,EL-DESOUKI Doaa S.,ABOUL-GHEIT Noha A.K...沸石催化甘蔗渣裂解制备多壁碳纳米管[J].燃料化学学报,2021,49(10):1421-1434,14.基金项目
The project was supported by the Science and Technology Development Fund(STDF)in Egypt(34830). （STDF）
