物理化学学报2021，Vol.37Issue(11)：114-124,11.DOI:10.3866/PKU.WHXB202006017
含氮金属有机框架衍生的铜基催化剂电催化还原二氧化碳
Cu-Based Catalyst Derived from Nitrogen-Containing Metal Organic Frameworks for Electroreduction of CO2
摘要
Abstract
With the development of human society and economy,the demand for energy resources has also increased rapidly.However,the use of traditional fossil energy leads to high amounts of carbon dioxide emissions,causing severe greenhouse effects.This,in turn,triggers a series of environmental problems.Harnessing renewable energy such as solar energy,wind energy,and hydropower to replace the traditional energy sources is very urgent.Conversion CO2 into value-added fuels and chemicals could be a useful strategy to mitigate the current energy and environmental crisis.It is well known that Cu-based materials are good electrocatalysts for the electrochemical reduction of CO2(ECR-CO2).However,they suffer from some disadvantages such as high overpotential and poor selectivity and durability.Therefore,the development of copper based electrocatalysts with high activity and selectivity is essential.Metal-organic frameworks(MOFs)materials that have the advantages of large specific surface area,tunable pore size and porosity,and highly dispersed unsaturated metal centers can be used as electrocatalysts for CO2 reduction or as precursors for further preparation of catalysts with excellent performance.Through thermal decomposition in an inert atmosphere,metal ions in MOF can be transformed into metal clusters,metal oxides,or even metal mono-atoms.Meanwhile,organic ligands are carbonized into porous carbon materials.The addition of some heteroatoms such as B,N,P,and S to carbon materials has also been shown to be effective in changing the electron state and coordination structure of the catalysts.These heteroatoms combine with carbon atoms to form a new active site,denoted as M-X-C(M is the central metal ion and X is the mixed heteroatom)to enhance the catalytic activity of the ECR-CO2.Herein,pre-synthesized Cu-NBDC MOF(a Cu-based MOF synthesized by using 2-aminoterephthalic acid(NBDC)as ligand)is used as a precursor to anchor Cu2O/Cu on nitrogen doped porous carbon(Cu2O/Cu@NC)by annealing at different temperatures.XPS analysis shows that the Cu-N content in Cu2O/Cu@NC decreases with increasing annealing temperature.Investigation of the ECR-CO2 reveals that Cu2O/Cu@NC can inhibit the HER more effectively compared to Cu2O/Cu@C,thereby improving the overall catalytic activity and multi-electron product selectivity of the ECR-CO2.While the Faradic efficiency of formate(FEformate)increases with increasing temperature,those of ethylene and methane(FEC2H4 and FECH4,respectively)decreases with increasing temperature.Specifically,upon annealing at 400℃,the CO2 Faradic efficiency of Cu2O/Cu@NC-400 is higher than 86％(-1.4 to-1.6 V vs.RHE),including 20.4％of FEC2H4(-1.4 V vs.RHE)and 23.9％of FECH4(-1.6 V vs.RHE).By contrast,FEcH4(-1.6 V vs.RHE)in the presence of Cu2O/Cu@C-400 without nitrogen doping is only 2.33％,and no C2H4 is detected.These significant differences in the catalytic behavior can be attributed to the fact that Cu-N is conducive for the stable adsorption of the *CH2 intermediate during the ECR-CO2,thus inhibiting the evolution of H2.These results indicate that the pathway of the ECR-CO2 and its performance can be effectivel regulated by complexing nitrogen with Cu motifs.关键词
铜基MOFs材料/氮掺杂/Cu2O/Cu/二氧化碳还原Key words
Copper-based MOFs material/Nitrogen doping/Cu2O/Cu/CO2 reduction分类
化学化工引用本文复制引用
金惠东,熊力堃,张想,连跃彬,陈思,陆永涛,邓昭,彭扬..含氮金属有机框架衍生的铜基催化剂电催化还原二氧化碳[J].物理化学学报,2021,37(11):114-124,11.基金项目
The project was supported by the National Natural Science Foundation of China(21701118),Major Project of Natural Science Research in Universities of Jiangsu Province,China(18KJA480004),Six Talent Peak Programs in Jiangsu Province,China(XCL-057,XCL-062,TD-XCL-006).国家自然科学基金(21701118),江苏省高校自然科学研究重大项目(18KJA480004),江苏省六大人才高峰计划(XCL-057,XCL-062,TD-XCL-006)资助 （21701118）
