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微波烧结制备ZrO2-AlN复合陶瓷的微观结构与性能研究

牟庭海 许文涛 凌军荣 董天文 秦梓轩 周有福

无机材料学报2021,Vol.36Issue(11):1231-1236,6.
无机材料学报2021,Vol.36Issue(11):1231-1236,6.DOI:10.15541/jim20210150

微波烧结制备ZrO2-AlN复合陶瓷的微观结构与性能研究

Microstructure and Properties of ZrO2-AlN Composite Ceramics by Microwave Sintering

牟庭海 1许文涛 2凌军荣 2董天文 3秦梓轩 2周有福2

作者信息

  • 1. 福建师范大学 化学与材料学院, 福州 350007
  • 2. 中国科学院 福建物质结构研究所, 光电材料化学与物理重点实验室, 福州 350002
  • 3. 福建光电信息科技创新实验室, 福州 350108
  • 折叠

摘要

Abstract

Zirconia (ZrO2) ceramics have excellent mechanical properties, but its application is limited by ZrO2-AlN low thermal conductivity (TC). Zirconia-aluminum nitride (AlN) composite ceramics ZrO2-AlN with high TC were designed and successfully fabricated by microwave sintering. After optimization of preparation conditions, the reaction between two substances was inhibited and the dense composite (relative density>99%) was obtained. The microstructure evolution, thermal behavior and mechanical properties were investigated in detail. The room temperature thermal conductivity, thermal diffusion coefficient and thermal capacity of ZrO2-AlN composites increase with AlN content increasing, reaching 41.3 W/(m·K), 15.2 mm2/s and 0.6 J/(g·K), respectively. Such ZrO2-AlN composites with high thermal conductivity and improved thermal shock resistance have broad application prospects in the field of high temperature heat exchange materials of energy systems.

关键词

氧化锆/氮化铝/复合陶瓷/微波烧结/热导率

Key words

zirconia/aluminum nitride/composite ceramic/microwave sintering/thermal conductivity

分类

化学化工

引用本文复制引用

牟庭海,许文涛,凌军荣,董天文,秦梓轩,周有福..微波烧结制备ZrO2-AlN复合陶瓷的微观结构与性能研究[J].无机材料学报,2021,36(11):1231-1236,6.

基金项目

Strategic Priority Research Program of the Chinese Academy of Sciences(XDB20010300,XDA21010204) (XDB20010300,XDA21010204)

Adv.Energy Sci.&Technol.Guangdong Lab(Open laboratory) (Open laboratory)

无机材料学报

OA北大核心CSCDCSTPCDSCI

1000-324X

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