新型炭材料2022,Vol.37Issue(1):109-135,27.DOI:10.1016/S1872-5805(22)60586-9
金属有机骨架和共价有机骨架及其衍生物用于超级电容器电极材料的研究进展
Research progress on metal and covalent organic framework-based materials for high-performance supercapacitors
摘要
Abstract
Metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) are both a series of crystalline porous materials. MOFs, COFs and their derivatives have attracted much attention in energy storage devices due to their highly ordered structures, large surface areas, tunable pore sizes and topologies, and well-defined redox-active porous skeletons. They must also have structural stability, an abundance of redox-active sites and high electronic conductivity for use in high-performance supercapacitor electrodes. We review the recent research progress on the design of MOFs and COFs, and their hybrids with conductive materials (e.g. conductive polymer, graphene and carbon nanotubes), and MOF- and COF-derived carbon materials. Their chemical and physical properties, capacitive performance and structure-property relationships are discussed. Finally, the challenges and prospects of MOF- and COF-based electrode materials are presented.关键词
金属有机骨架/共价有机骨架/杂化材料/衍生炭/超级电容器Key words
Metal-organic frameworks/Covalent organic frameworks/Hybrid/Derived carbon/Supercapacitors分类
通用工业技术引用本文复制引用
王帅,郭玉哲,王芳霄,周圣虎,曾天宇,董育斌..金属有机骨架和共价有机骨架及其衍生物用于超级电容器电极材料的研究进展[J].新型炭材料,2022,37(1):109-135,27.基金项目
This work was financially supported by the Na-tional Natural Science Foundation of China(21701103). (21701103)