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X射线吸收谱测算锂氮共掺杂氧化锌薄膜局域电子结构

申赫 王岩岩 高铭 李东飞

发光学报2022,Vol.43Issue(2):218-225,8.
发光学报2022,Vol.43Issue(2):218-225,8.DOI:10.37188/CJL.20210365

X射线吸收谱测算锂氮共掺杂氧化锌薄膜局域电子结构

Local Electronic Structure of Lithium Nitrogen Codoped ZnO Films Revealed by X-ray Absorption Fine Structure Spectroscopy

申赫 1王岩岩 2高铭 3李东飞4

作者信息

  • 1. 吉林师范大学 功能材料物理与化学教育部重点实验室, 吉林 长春 130103
  • 2. 吉林师范大学 物理学院, 吉林 四平 136000
  • 3. 吉林师范大学 环境友好材料制备与应用教育部重点实验室,吉林 长春 130103
  • 4. 吉林师范大学 化学学院,吉林 四平 136000
  • 折叠

摘要

Abstract

It is to reveal the formation mechanism of Li and N codoped p-ZnO films and the cause for the stable p-type conductivity. The films has been studied by investigating their local electronic structures using X-ray photoelec-tron spectroscopy and X-ray absorption fine structure spectroscopy based on synchrotron radiation source. The signals of Li—N bond and Li—N complex acceptors in the p-ZnO films have been collected, and the acceptor level estimated from photoluminescence spectroscopy is about 122 meV. The formation of Li—N complex acceptors has been con-firmed, and the realization of Li—N bond has been attributed to the origin of the good stability of the p-type ZnO films obtained by Li, N codoping method.

关键词

氧化锌/p型掺杂/形成机制/稳定性/X射线吸收精细结构谱

Key words

zinc oxide/p-type doping/formation mechanism/stability/X-ray absorption fine structure spectroscopy

分类

数理科学

引用本文复制引用

申赫,王岩岩,高铭,李东飞..X射线吸收谱测算锂氮共掺杂氧化锌薄膜局域电子结构[J].发光学报,2022,43(2):218-225,8.

基金项目

国家自然科学基金(61704065,61705078,11904130)资助项目Supported by National Natural Science Foundation of China(61704065,61705078,11904130) (61704065,61705078,11904130)

发光学报

OA北大核心CSCDCSTPCD

1000-7032

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