物理学进展2022，Vol.42Issue(1)：17-26,10.DOI:10.13725/j.cnki.pip.2022.01.002
大尺寸硫醇配体保护金团簇的激发态动力学研究
Excited-State Dynamics of Large-Sized Thiolate-Protected Aun (n>100) Nanoclusters
摘要
Abstract
Gold nanoclusters (size <2.2 nm) bridge metallic gold nanoparticles and single gold atoms, playing a crucial role in revealing the origin of surface plasmon resonance and metallic bonding. Ligand-protected gold nanoclusters provide a suitable platform to under-stand metal to non-metal transitions while the excited-state dynamics of gold nanoclusters in the transition regime remain elusive. In this minireview, I summarize the excite-state dynamics of large-sized Aun (n > 100) nanoclusters and compare them with those of plas-monic gold nanoparticles. By looking into the electron and vibration dynamics of a series of thiolate-protected gold nanoclusters in the transition regime, the electronic structures of these nanoclusters are further discussed. A deeper understanding of the mechanism of elec-tron relaxation and energy dissipation of large-sized gold nanoclusters will be of great help to connect the optical properties of metal clusters and nanoparticles, which will further promote the design of those functional nanomaterials.关键词
金团簇/激发态动力学/电子结构/表面等离子共振Key words
gold nanoclusters/excited-state dynamics/electronic structure/surface plasmon resonance分类
数理科学引用本文复制引用
周蒙..大尺寸硫醇配体保护金团簇的激发态动力学研究[J].物理学进展,2022,42(1):17-26,10.基金项目
This work was supported by the startup funding from University of Science and Technology of China and the Chinese Academy of Sciences(Grant No.KY2340000137). （Grant No.KY2340000137）
