电化学2022，Vol.28Issue(1)：1-12,12.DOI:10.13208/j.electrochem.210621
磷化物助力铂基催化剂甲醇电氧化的研究进展
Advances of Phosphide Promoter Assisted Pt Based Catalyst for Electrooxidation of Methanol
摘要
Abstract
Transition metal phosphide (TMP),as an ideal catalytic promoter in methanol fuel oxidation,has received increased attention because of its multifunctional active sites,tunable structure and composition,as well as unique physical and chemical properties and efficient multi-composition synergistic effect.Some advances have been made for this catalyst system recently.In the current review,the research progresses of transition metal phosphides (TMPs) in the assisted electrooxidation of methanol including the catalysts fabrication and their performance evaluation for methanol oxidation are reviewed.The promotion effect of TMPs has been firstly presented and the catalyst systems based on the different metal centers of TMPs are then mainly discussed.It is conclud-ed that the TMPs can greatly promote methanol oxidation through the electronic effect and the oxyphilic property based on the bi-functional catalytic mechanism.The problems and challenges in methanol fuel oxidation by using TMPs are also described at the end with the attention being paid to the precise catalyst design.The catalytic mechanism probing and application of the fuel cells device are proposed.The current effort might be helpful to the community for novel catalyst system design and fabrication.关键词
过渡金属磷化物/甲醇氧化反应/促进剂/电催化Key words
transition metal phosphide/methanol oxidation reaction/promoter/electrocatalysis引用本文复制引用
李萌,冯立纲..磷化物助力铂基催化剂甲醇电氧化的研究进展[J].电化学,2022,28(1):1-12,12.基金项目
The work is supported by the National Natural Science Foundation of China (21972124,21603041)and the Priority Academic Program Development of Jiangsu Higher Education Institution. （21972124,21603041）
