新型炭材料2022，Vol.37Issue(4)：734-742,9.DOI:10.1016/S1872-5805(21)60061-6
石墨烯负载单原子钴催化剂的制备及其电催化二氧化碳还原反应性能
CoN4 active sites in a graphene matrix for the highly efficient electrocatalysis of CO2 reduction
摘要
Abstract
Developing highly selective, economical and stable catalysts for the electrochemical conversion of CO2 into value-ad-ded carbon products to mitigate both CO2 emission and the energy crisis is challenging. We report an efficient and robust electrocata-lyst for the CO2 reduction reaction (CO2RR) by embedding CoN4 active sites in a graphene matrix. These highly dispersed CoN4 sites show an extraordinary CO2RR activity, with a high CO Faradaic efficiency of nearly 95％ at ?0.76 V (vs. RHE) and remarkable dur-ability. The corresponding overpotential is 0.65 V. Our finding could pave the way for the design at the atomic scale of highly effi-cient electrocatalysts for the CO2RR.关键词
CO2还原/钴/单原子催化/电化学/石墨烯Key words
CO2 electroreduction/Cobalt/Single-atom catalysts/Electrochemistry/Graphene分类
通用工业技术引用本文复制引用
张会念,王慧奇,贾素萍,常青,李宁,李莹,施箫琳,李子源,胡胜亮..石墨烯负载单原子钴催化剂的制备及其电催化二氧化碳还原反应性能[J].新型炭材料,2022,37(4):734-742,9.基金项目
The authors thank for the financial support from the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi(2019L0597,2019L0557,2020L0279),the National Natural Science Foundation of China(21703209),the Shanxi Province Science Foundation for Youths(201901D211225),the Talent Introduction Fund of Shanxi Province(18001913),the starting fund for scientific research of North University of China(11012316),the project supported by Science Foundation of North University of China(XJJ201819,XJJ201913)and the Key Research and Development(R&D)Projects of Shanxi Province(201803D121037). （2019L0597,2019L0557,2020L0279）
