燃料化学学报2023，Vol.51Issue(1)：85-100,16.DOI:10.1016/S1872-5813(22)60055-0
二氧化碳合成杂环噁唑烷酮的研究进展
Recent advances on oxazolidinones synthesize from carbon dioxide
摘要
Abstract
Carbon dioxide capture and utilization (CCU) is the best way to solve the problem of reducing concentration of carbon dioxide in the atmosphere, and it has a good prospect for development. On this basis, chemical researchers have explored the methods of synthesizing valuable organic compounds with CO2 as carbon source. The oxazolidinones are commonly used to synthesize drugs, and they are significant in organic synthesis as chiral molecules and intermediates. The synthetic methods of oxazolidinones have emerged in recent years. Furthermore, the methods of using carbon dioxide as a carbon source have attracted many researchers. In earlier years, people explored cycloaddition reactions of carbon dioxide and aziridines to synthesize oxazolidinones, and they took alkali metals, Cr, Al or other metals as catalysts to improve the efficiency of the reactions. Because of the cost and the principle of green synthesis, it is more suitable for large-scale reaction to select cheap and easily available ionic liquids or no catalysts. In addition, carbon dioxide and compounds such asβ-amino alcohols, unsaturated amines and 1, 2-dihalohydrogenated compounds can obtain moderate or even excellent yields under different reaction conditions. In this paper, we summarized the synthetic methods of oxazolidinones using CO2 with different raw materials in recent years.关键词
二氧化碳/噁唑烷酮/杂环丙啶/环氧乙烷/2-氨基醇Key words
carbondioxide/oxazolidinones/aziridines/epoxides/β-aminoalcohols分类
化学化工引用本文复制引用
王变玲,郭志强,魏学红..二氧化碳合成杂环噁唑烷酮的研究进展[J].燃料化学学报,2023,51(1):85-100,16.基金项目
The project was supported by the Fundamental Research Program of Shanxi Province(20210302123446). （20210302123446）
