新型炭材料2023，Vol.38Issue(1)：200-210,11.DOI:10.1016/S1872-5805(22)60609-7
金属有机骨架(ZIF-8@ZIF-67)衍生的Co/N共掺杂碳基催化剂在氧还原反应(ORR)中的应用
A carbon catalyst doped with Co and N derived from the metal-organic framework hybrid(ZIF-8@ZIF-67)for efficient oxygen reduction reaction
摘要
Abstract
Carbon-based catalysts for the oxygen reduction reaction(ORR)are considered potential substitutes for the expensive platinum-based catalysts.Recently,transition metal and nitrogen co-doped carbon materials(M-N-C)have attracted much attention from researchers due to their low cost and excellent activity.A cobalt-and nitrogen-co-doped porous carbon material(Co-N@CNT-C800)was prepared by the simple one-step pyrolysis of a star fruit-like MOF hybrid(ZIF-8@ZIF-67)at 800 ℃.It consisted of CNTs with substantial Co and N co-doping and had a large surface area(428 m2·g?1).It had an excellent half-wave potential and good current density in alkaline media in the ORR with values of 0.841 V and 5.07 mA·cm?2,respectively.Compared with commer-cial Pt/C materials it also had excellent electrochemical stability and methanol tolerance.This research provides an effective way to fabricate low cost,high activity electrocatalysts for use in energy conversion.关键词
N掺杂/碳纳米管/金属有机骨架/电催化剂/氧还原反应Key words
N-doped/Carbon nanotubes/Metal-organic frameworks/Electrocatalyst/Oxygen reduction reaction分类
通用工业技术引用本文复制引用
张亚婷,李思祎,张娜娜,林港,王瑞琪,杨梦囡,李可可..金属有机骨架(ZIF-8@ZIF-67)衍生的Co/N共掺杂碳基催化剂在氧还原反应(ORR)中的应用[J].新型炭材料,2023,38(1):200-210,11.基金项目
This work was supported by the National Natur-al Science Foundation of China(U1810113 and U1703251) （U1810113 and U1703251）
Natural Science Foundation of Shaanxi(2019JLP-12),Shaanxi Provincial Innovation Capab-ility Support Program(2019TD-021).国家自然科学基金项目(U1810113,U1703251) （2019JLP-12）
陕西省自然科学基金项目(2019JLP-12),陕西省创新能力支持计划项目(2019TD-021). （2019JLP-12）
