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四种混合不同碳材料的FOX-7粉末激光点火:点火延迟实验与简化计算

李恒 郝海霞 赵凤起 徐司雨 姜菡雨 裴庆 王长健 张蕊 张洋 马晓迅

火炸药学报2023,Vol.46Issue(2):163-171,9.
火炸药学报2023,Vol.46Issue(2):163-171,9.DOI:10.14077/j.issn.1007-7812.202206001

四种混合不同碳材料的FOX-7粉末激光点火:点火延迟实验与简化计算

Laser Ignition of Four Types of FOX-7 Powders Mixed with Different Carbon Materials:Experiments and Simplified Calculations of Ignition Delays

李恒 1郝海霞 1赵凤起 1徐司雨 1姜菡雨 1裴庆 1王长健 1张蕊 2张洋 1马晓迅3

作者信息

  • 1. 西安近代化学研究所燃烧与爆炸技术重点实验室,陕西西安710065
  • 2. 陕西应用物理化学研究所应用物理化学重点实验室,陕西西安710061
  • 3. 西北大学化工学院,陕西西安710069
  • 折叠

摘要

Abstract

The ignition experiments of four types of FOX-7 (1 ,1-diamino-2 ,2-dinitroethene) powders mixed with different carbon materials were carried out by a CO2 laser over a certain range of power density to study the trend of ignition delay times ,aiming at the relatively difficult ignition performance of FOX-7 hindering extensive applications .The calculations and a- nalysis of ignition delay times were conducted by two simplified ignition models to gain insight into the ignition mechanism and guide the ignition performance improvement of FOX-7 .It is experimentally observed that the ignition delay time of FOX-7 powder reduced to different extents due to the addition of carbon materials .Graphene and graphene oxide exhibit relatively strong promoting role in shortening the ignition delay time and graphite has a slight effect .The calculation results show that Model 1 is more suitable for effectively predicting the ignition delay time of FOX-7 powder than Model 2 .The mechanism anal- ysis indicates that the addition of graphene could efficiently improve the absorption of radiation energy by FOX-7 powder and reduce energy loss .The main ignition induced process of FOX-7 sample was intensively affected by the heat transfer properties under laser irradiation .

关键词

物理化学/FOX-7/碳材料/激光点火/点火延迟/简化计算

Key words

physical chemistry/FOX-7/carbon material/laser ignition/ignition delay/simplified calculation

分类

军事科技

引用本文复制引用

李恒,郝海霞,赵凤起,徐司雨,姜菡雨,裴庆,王长健,张蕊,张洋,马晓迅..四种混合不同碳材料的FOX-7粉末激光点火:点火延迟实验与简化计算[J].火炸药学报,2023,46(2):163-171,9.

基金项目

National Natural Science Foundation of China(No.21473130 ()

No.52027809) ()

火炸药学报

OA北大核心CSCDCSTPCD

1007-7812

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