燃料化学学报（中英文）2023，Vol.51Issue(4)：415-427,13.DOI:10.1016/S1872-5813(22)60047-1
二氧化碳高值利用合成苯氨基甲酸甲酯
CO2 valorization through methyl N-phenylcarbamate synthesis
摘要
Abstract
Methyl N-phenylcarbamate(MPC)is an important intermediate for the synthesis of diphenylmethane diisocyanate(MDI),and its preparation using CO2 or its equivalents/derivatives as carbon source represents a green and sustainable manner for fine chemicals synthesis.This review will highlight the development of MPC synthetic methods from the viewpoint of chemical fixation of CO2.The contents mainly include the introduction of MPC synthesis through CO2 equivalents(urea or phenyl urea)alcoholysis,dimethyl carbonate(DMC)aminolysis,and the coupling of DMC and diphenyl urea.Furthermore,one-pot synthesis of carbamates/MPC from aliphatic amines/aniline,CO2 and alcohols is highlighted which represents one of the most promising schemes in direct CO2 utilization.What is more,the reaction mechanisms and selection of catalysts are also discussed in detail.The advances will provide important theories on further improving the efficiency of green catalysis and sustainable chemical processes.关键词
二氧化碳/CO2 等价物/苯氨基甲酸甲酯/催化/合成方法Key words
carbon dioxide/CO2 equivalent/methyl N-phenylcarbamate/catalysis/synthetic method分类
化学化工引用本文复制引用
荀家瑶,宋清文,张乾霞,韩丽华,张侃,张建利,刘平..二氧化碳高值利用合成苯氨基甲酸甲酯[J].燃料化学学报（中英文）,2023,51(4):415-427,13.基金项目
The project was supported by the Natural Science Foundation of Shanxi(20210302123002),Technical Research and Development Project from Lu'an Chemical Industry Group Co.,Ltd.(2021A0105005)and the Foundation of State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering(2022-K20). （20210302123002）
