井冈山大学学报（自然科学版）2023，Vol.44Issue(2)：30-37,8.DOI:10.3969/j.issn.1674-8085.2023.02.005
一种含5-硝基间苯二甲酸和菲咯啉配体的超分子化合物:结构表征,光致发光和电化学性能
A SUPRAMOLECULAR COMPLEX OF 5-NITRO-ISOPHTHALIC ACID AND PHEN MIXED LIGANDS:CHARACTERIZATION,PHOTOLUMINESCENT AND ELECTROCHEMICAL PROPERTIES
摘要
Abstract
A copper supramolecular complex with mixed ligands,[CuClPhen]+·[HL]-·2H2O(H2L = 5-Nitro-isophthalic acid,Phen = 1,10-phenanthroline)has been synthesized by a hydrothermal approach and its structure was determined by single-crystal X-ray crystallography.The title copper complex crystallizes in triclinic space group P-1 Crystal data for the title complex:C32H24ClN5CuO8,Mr= 704.54,a = 10.4044(5),b = 12.3912(9),c = 12.4632(9)?,α = 73.859(6),β = 85.036(5),γ= 78.202(5)°,V= 1510.09(17)?3,Z= 2,T= 293(2)K,Dc= 1.549 g/cm3,μ(Mo Kα)= 0.874 mm-1,F(000)= 720.0,R = 0.0554,wR = 0.1434,and GOF = 1.098.When used as the electrode material of the super-capacitors,the as-prepared complex showed high specific capacitance,good cycle stability and excellent rate performance.Specifically,the maximum specific capacitance can achieve 69 F/g in 1 mol/L KOH solution.At the current density of 2 A/g,the retention of specific capacitance was 72%after 10000 cycles.The title complex is a potential red photoluminescent material.关键词
超分子化合物/晶体结构/电化学性能Key words
preparation/characterization/photoluminescence/electrochemical properties/copper complex分类
化学化工引用本文复制引用
黄敬平,郭瑾,刘若兰,陈斐,吴文弛,王子扬,胡于涛,孙乌尼尔..一种含5-硝基间苯二甲酸和菲咯啉配体的超分子化合物:结构表征,光致发光和电化学性能[J].井冈山大学学报（自然科学版）,2023,44(2):30-37,8.基金项目
the National Natural Science Foundation of China(22168018) （22168018）
the Natural Science Foundation of Jiangxi Province of China(20202BAB204203),and the Natural Science Foundation of Ji'an,Jiangxi Province of China(2021-8-8) （20202BAB204203）
