高等学校化学学报2023，Vol.44Issue(5)：225-249,25.DOI:10.7503/cjcu20220740
过渡金属氧化物插层化学及其电催化应用的新进展
Recent Progress in Intercalation Chemistry of Transition Metal Oxides for Electrocatalytic Applications
摘要
Abstract
Intercalation chemistry describes the process by which a guest is intercalated into a host to form an inter? calated compound. Intercalation chemistry, as an effective method to modify structures, has been intensively studied in recent centuries for electrocatalysis-based energy storage and conversion devices. Particularly, research on transi? tion metal oxides(TMOs) has become an emerging frontier in intercalation chemistry because of their tunability in structure and composition. Nonetheless, confusions remain in the discovery of indefinable intercalation mechanism and unexplained properties change. In this paper, a first-ever in-depth description of the intercalation mechanism, which directly determines the potential of properties and applications, will be presented. We discuss the major synthesis strategies for TMOs intercalation compounds. We summarize the recent advances for electrocatalytic appli? cations of intercalated TMOs. Moreover, this review will be concluded with a section on the future opportunities and challenges for intercalation of TMOs.关键词
插层化学/过渡金属氧化物/电催化Key words
Intercalation chemistry/Transition metal oxide/Electrocatalysis分类
化学化工引用本文复制引用
池丽萍,牛壮壮,廖洁,唐凯斌,高敏锐..过渡金属氧化物插层化学及其电催化应用的新进展[J].高等学校化学学报,2023,44(5):225-249,25.基金项目
国家重点研发计划项目(批准号:2018YFA0702001)、 国家自然科学基金(批准号:22225901,21975237,22175162)、 安徽省重点研究与开发计划项目(批准号:202004a05020073)、 中央高校基本科研业务费专项基金(批准号:WK2340000101)和稀土资源利用国家重点实验室开放课题(批准号:RERU2022007)资助.Supported by the National Key Research and Development Program of China(No.2018YFA0702001),the National Natural Science Foundation of China(Nos.22225901,21975237,22175162),the Anhui Provincial Research and Development Program,China(No.202004a05020073),the Fundamental Research Funds for the Central Universities,China(No.WK2340000101)and the Open Funds of the State Key Laboratory of Rare Earth Resource Utilization,China(No.RERU2022007). （批准号:2018YFA0702001）
