物理化学学报2023，Vol.39Issue(4)：1-11,11.DOI:10.3866/PKU.WHXB202210025
电催化动力学简介
Introduction to Electrocatalytic Kinetics
摘要
Abstract
Electrocatalytic reactions and processes are expected to be major drivers in society's shift toward renewable energy and chemicals.Electrocatalytic kinetic analysis is an accessible and informative technique to interrogate reaction mechanisms and establish structure-activity relationships.In this tutorial,we discuss general procedures,implicit assumptions,and potential pitfalls when conducting the Tafel analysis in the context of three widely investigated electrocatalytic reactions,i.e.,the electrochemical CO2,CO,and O2 reduction reactions.Basic concepts and relations among key thermodynamic and kinetic variables are also covered to help interpret the activation parameters of electrochemical reactions.关键词
电催化/反应动力学/电化学活化参数Key words
Electrocatalysis/Reaction kinetics/Electrochemical activation parameter分类
化学化工引用本文复制引用
许义飞,杨瀚文,常晓侠,徐冰君..电催化动力学简介[J].物理化学学报,2023,39(4):1-11,11.基金项目
This work is supported by the Beijing National Laboratory for Molecular Sciences.北京分子科学国家研究中心资助 （）
