新型炭材料2023，Vol.38Issue(3)：543-554,12.DOI:10.1016/S1872-5805(23)60726-7
基于废弃生物质原位合成蜂窝状镶嵌ZnS纳米点的N-S共掺杂炭纳米片的制备及其锂离子电池性能
The in situ formation of ZnS nanodots embedded in honeycomb-like N-S co-doped carbon nanosheets derived from waste biomass for use in lithium-ion batteries
摘要
Abstract
A nanocomposite of zinc sulfide nanodots imbedded in honeycomb-like N-S co-doped carbon nanosheets(ZnS/NS-CN)was synthesized from waste biomass orange peel using ZnCl2 as the hard template and zinc source,and melamine and thiourea as the respective nitrogen and sulfur sources.When used as the anode material in Li-ion batteries,ZnS/NS-CN has a high reversible capacity(853.5 mAh g-1 at 0.1 A g-1 after 300 cycles),an excellent long-term cycling stability(70.1%capacity retention after 1 000 cycles at 5 A g-1)and an outstanding rate capability.Besides,a ZnS/NS-CN//LiNiCoMnO2 full cell tested at 0.5-4 V has an ex-cellent battery performance(140.4 mAh g-1 at 0.2 C after 150 cycles with an energy density of 132.4 Wh kg-1).关键词
ZnS纳米点/N-S共掺杂炭纳米片/废弃生物质/锂离子电池Key words
ZnS nanodots/N-S co-doped carbon nanosheets/Waste biomass/Li-ion batteries分类
通用工业技术引用本文复制引用
余秋香,李焕新,文永亮,徐晨曦,秦石峰,旷亚非,周海晖,黄中原..基于废弃生物质原位合成蜂窝状镶嵌ZnS纳米点的N-S共掺杂炭纳米片的制备及其锂离子电池性能[J].新型炭材料,2023,38(3):543-554,12.基金项目
This work was supported by National Natural Science Foundation of China(52274298,51974114,51672075,21908049),China Postdoctoral Science Foundation(2020M682560),Hunan Provincial Natur-al Science Foundation of China(Grant No.2020JJ4175),Science&technology innovation pro-gram of Hunan Province(2020RC2024)and the Fun-damental Research Funds for the Central Universities.国家自然科学基金项目(52274298,51974114,51672075,21908049) （52274298,51974114,51672075,21908049）
中国博士后科学基金(2020M682560) （2020M682560）
湖南省自然科学基金(2020JJ4175) （2020JJ4175）
湖南省科技创新计划(2020RC2024)和中央高校基础研究经费. （2020RC2024）
