Engineering Spin States of Isolated Copper Species in a Metal-Organic Framework Improves Urea ElectrosynthesisOA

作者：Yuhang Gao;Jingnan Wang;Yijun Yang;Jian Wang;Chuang Zhang;Xi Wang;Jiannian Yao

作者单位：Key Laboratory of Photochemistry,Beijing National Laboratory for Molecular Sciences,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190,People's Republic of China||University of Chinese Academy of Sciences,Beijing 100049,People's Republic of ChinaMolecular Plus and Collaborative Innovation Center of Chemical Science and Engineering,Tianjin University,Tianjin 300072,People's Republic of ChinaDepartment of Physics,School of Physical Science and Engineering,Beijing Jiaotong University,Beijing 100044,People's Republic of ChinaResearch Center for Magnetic and Spintronic Materials National Institute for Materials Science,Tsukuba 305-0047,JapanKey Laboratory of Photochemistry,Beijing National Laboratory for Molecular Sciences,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190,People's Republic of China||University of Chinese Academy of Sciences,Beijing 100049,People's Republic of ChinaDepartment of Physics,School of Physical Science and Engineering,Beijing Jiaotong University,Beijing 100044,People's Republic of ChinaKey Laboratory of Photochemistry,Beijing National Laboratory for Molecular Sciences,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190,People's Republic of China||University of Chinese Academy of Sciences,Beijing 100049,People's Republic of China

中文关键词：ElectrocatalysisUrea synthesisMetal-organic frameworkSpin catalysisC-N coupling

英文关键词：ElectrocatalysisUrea synthesisMetal-organic frameworkSpin catalysisC-N coupling

刊名：《纳微快报（英文）》 2023 (9)

相关项目：同步辐射高分辨XAS研究磁性贵金属合金团簇的成核和生长过程

页码/页数：536-549,14

基金：This work was supported by"Key Pro-gram for International S&T Cooperation Projects of China"from the Ministry of Science and Technology of China(Grant No.2019YFE0123000),the National Natural Science Foundation of China(Grant Nos.91961125 and 21905019),Science and Technol-ogy Project of Guangdong Province(No.2020B0101370001),and Chemistry and Chemical Engineering Guangdong Laboratory(No.1932004)and the Project from China Petrochemical Corporation(No.S20L00151).We thank the beamlines 1W1B and 4W1B at Beijing Synchrotron Radiation Facility(BSRF).Open access funding provided by Shanghai Jiao Tong University.

DOI：10.1007/s40820-023-01127-0