物理化学学报2023，Vol.39Issue(10)：31-56,26.DOI:10.3866/PKU.WHXB202305030
乙炔半加氢催化剂设计
Catalyst Design for Acetylene Semi-Hydrogenation
摘要
Abstract
Traces of acetylene impurities in the feed gas during the subsequent industrial production process of polyethylene will inactivate ethylene polymerization.The semi-hydrogenation of acetylene to ethylene has been proved to be one of the most effective technologies for the purification of ethylene.Pd catalysts have been playing a leading role in industrial applications due to their excellent performance.However,as Pd is a precious metal,Pd catalysts are expensive.Thus,it is very important to design low-cost,high-selectivity,and high-conversion acetylene semi-hydrogenation catalysts.Here,we summarize the influence of single-metal catalysts based on the acetylene semi-hydrogenation mechanism.The hydrogenation ability of the catalysts should be neither too high nor too low.When other metals are added to palladium catalysts,bimetallic catalysts are formed,which can be classified into typical substitutional solid-solution alloy catalysts,intermetallic compound catalysts,and single-atom alloy catalysts.Regarding the influence of bimetallic catalysts on the performance of acetylene hydrogenation,metals other than Pd have different effects on the acetylene hydrogenation process due to the different structure and environment.While,the structure of the catalyst and the chemical environment ultimately affect the electronic structure of the active center of the catalyst.Based on this,we conclude that the key to the semi-hydrogenation of acetylene is the charge density of the active center of the catalyst,such as dual-atom sites and nano-single atoms;the electrons control the active center of the catalyst.Finely turning the electronic structure of single metal active sites will improve their catalytic activity,selectivity,and stability of the catalyst for acetylene semi-hydrogenation.Additionally,we propose a possible future direction for the development of high-performance acetylene semi-hydrogenation catalysts.Future catalysts for acetylene semi-hydrogenation able to precisely control the active sites to improve their catalytic activity,selectivity,and stability are the focus of researchers,such as the precise control of single-atom-site,dual-atom-site,and nano-single-atom-site catalysts.关键词
乙炔/乙烯/选择性加氢/催化剂Key words
Acetylene/Ethylene/Selective hydrogenation/Catalyst分类
化学引用本文复制引用
方洪燕,江静静,王定胜,刘向文,朱敦如,李亚栋..乙炔半加氢催化剂设计[J].物理化学学报,2023,39(10):31-56,26.基金项目
The project was supported by the National Natural Science Foundation of China(22101150,22101029),Beijing Municipal Natural Science Foundation(2222006)Beijing Municipal Financial Project BJAST Scholar Programs B(BS202001),Beijing Municipal Financial Project BJAST Young Scholar Programs B(YS202202),and the State Key Laboratory of Coordination Chemistry(SKLCC2106).国家自然科学基金(22101150,22101029),北京市自然科学基金(2222006),北京市政金融项目BJAST学者项目B(BS202001),北京市政金融项目BJAST青年学者项目B(YS202202)及配位化学国家重点实验室(SKLCC2106)资助 （22101150,22101029）
