新型炭材料（中英文）2023，Vol.38Issue(5)：989-996,8.DOI:10.1016/S1872-5805(23)60728-0
二茂铁表面活性剂在聚丙烯腈基炭纤维表面的可逆修饰
Reversible surface modification of PAN-based carbon fibers by a ferrocene-based surfactant
摘要
Abstract
The surface of carbon fibers(CFs)was modified by a surfactant(ferrocenemethyl)dodecyldimethylammonium brom-ide(FDDA)to enhance the interfacial ashesion between the CFs and surrounding matrix.Results showed that it could be electro-chemically desorbed by a potentiostatic electro-oxidation method.The FDDA adsorption isotherm was attributed to the formation of multi-molecular layers mainly by non-electrostatic interactions.The adsorption and desorption of FDDA on the CFs have little effect on their tensile strength.The effects of FDDA modification on the interfacial properties of CF/epoxy composites were evaluated by a single-filament fragmentation test.Compared with the un-modified CFs,the FDDA-modified ones had significantly improved inter-facial adhesion properties in the composites.This method provides a potential approach for preparing recyclable CF/resin compos-ites.关键词
炭纤维/FDDA/可逆修饰/界面性能Key words
Carbon fibers/FDDA/Reversible modification/Interfacial properties分类
通用工业技术引用本文复制引用
张晓芳,姚婷婷,刘玉婷,吴刚平..二茂铁表面活性剂在聚丙烯腈基炭纤维表面的可逆修饰[J].新型炭材料（中英文）,2023,38(5):989-996,8.基金项目
Major Science and Technology Projects of Shanxi Province(20181101020),Independent Innova-tion Fund Project of Shanxi Institute of Coal Chem-istry-Basic Research Project Supported by ICC CAS(SCJC-HN-2022-15). 山西省科技重大专项项目(20181101020) （20181101020）
山西煤化所自主创新项目-基础研究项目(SCJC-HN-2022-15). （SCJC-HN-2022-15）
