化工进展2023，Vol.42Issue(11)：5585-5591,7.DOI:10.16085/j.issn.1000-6613.2022-2234
氯化溴的微反应连续合成与应用
Microreaction continuous synthesis and application of bromine chloride
摘要
Abstract
Bromine chloride is an important halogenating reagent in industry.Its synthesis has many challenges such as high heat release,low production efficiency and serious potential safety hazards.The continuity and miniaturization of producing equipment is an important development direction of bromine chloride synthesis technology.To develop microreaction technology for preparing bromine chloride via absorbing chlorine by means of dichloromethane solution of bromine,the mass transfer performances of Corning G1 reactor,Jinde C1 reactor and self-made micromixer + micro packed reactor were investigated.Continuous and stable preparation of bromine chloride was realized and the space-time yield of the microreactors reached 2.25g/(min∙mL).Bromination of polystyrene was implemented using the bromine chloride prepared from microreactors,and brominated polystyrene products with mass percentage>66% bromine content and 5% thermogravimetric temperature>370℃ were obtained.关键词
氯化溴/微反应器/连续合成/溴化聚苯乙烯Key words
bromine chloride/microreactor/continuous synthesis/brominated polystyrene分类
化学工程引用本文复制引用
王德强,李金忠,王凯,骆广生..氯化溴的微反应连续合成与应用[J].化工进展,2023,42(11):5585-5591,7.基金项目
国家自然科学基金(21991104) （21991104）
山东省重点研发计划(重大科技创新工程)(2020CXGC011206). （重大科技创新工程）
